X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine)

G.B. Deacon; T. Feng; P.C. Junk; Brian Skelton; Allan White

doi:10.1002/zaac.200600153

X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine)

G.B. Deacon, T. Feng, P.C. Junk, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Structures of the new complexes [La(Odpp)(3)(dig)]center dot 0.5dig (Odpp = 2,6-diphenylphenolate; dig = bis(2-methoxyethyl) ether - diglyme) and [Nd(Odpp)(3)(py)(2)]center dot 2py (py = pyridine), obtained by crystallization of the corresponding [Ln(Odpp)(3)(thf)(2)] complex from diglyme or pyridine contain six-coordinate and five-coordinate lanthanoid atoms respectively. In the former, two meridional sets of donor atoms, (O-3(dig) and O-3(Odpp)) are near normal to each other and in a highly distorted octahedral stereochemistry, whereas the latter is trigonal bipyramidal with an oxygen and a nitrogen atom apical and a pronounced lengthening of the axial Nd-N bond.

Original language	English
Pages (from-to)	1986-1988
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	632
Issue number	12-13
DOIs	https://doi.org/10.1002/zaac.200600153
Publication status	Published - 2006

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Deacon, G. B., Feng, T., Junk, P. C., Skelton, B., & White, A. (2006). X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine). Zeitschrift fur Anorganische und Allgemeine Chemie, 632(12-13), 1986-1988. https://doi.org/10.1002/zaac.200600153

Deacon, G.B. ; Feng, T. ; Junk, P.C. et al. / X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine). In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2006 ; Vol. 632, No. 12-13. pp. 1986-1988.

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title = "X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine)",

abstract = "Structures of the new complexes [La(Odpp)(3)(dig)]center dot 0.5dig (Odpp = 2,6-diphenylphenolate; dig = bis(2-methoxyethyl) ether - diglyme) and [Nd(Odpp)(3)(py)(2)]center dot 2py (py = pyridine), obtained by crystallization of the corresponding [Ln(Odpp)(3)(thf)(2)] complex from diglyme or pyridine contain six-coordinate and five-coordinate lanthanoid atoms respectively. In the former, two meridional sets of donor atoms, (O-3(dig) and O-3(Odpp)) are near normal to each other and in a highly distorted octahedral stereochemistry, whereas the latter is trigonal bipyramidal with an oxygen and a nitrogen atom apical and a pronounced lengthening of the axial Nd-N bond.",

author = "G.B. Deacon and T. Feng and P.C. Junk and Brian Skelton and Allan White",

year = "2006",

doi = "10.1002/zaac.200600153",

language = "English",

volume = "632",

pages = "1986--1988",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

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number = "12-13",

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Deacon, GB, Feng, T, Junk, PC, Skelton, B & White, A 2006, 'X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine)', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 632, no. 12-13, pp. 1986-1988. https://doi.org/10.1002/zaac.200600153

X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine). / Deacon, G.B.; Feng, T.; Junk, P.C. et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 632, No. 12-13, 2006, p. 1986-1988.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine)

AU - Deacon, G.B.

AU - Feng, T.

AU - Junk, P.C.

AU - Skelton, Brian

AU - White, Allan

PY - 2006

Y1 - 2006

N2 - Structures of the new complexes [La(Odpp)(3)(dig)]center dot 0.5dig (Odpp = 2,6-diphenylphenolate; dig = bis(2-methoxyethyl) ether - diglyme) and [Nd(Odpp)(3)(py)(2)]center dot 2py (py = pyridine), obtained by crystallization of the corresponding [Ln(Odpp)(3)(thf)(2)] complex from diglyme or pyridine contain six-coordinate and five-coordinate lanthanoid atoms respectively. In the former, two meridional sets of donor atoms, (O-3(dig) and O-3(Odpp)) are near normal to each other and in a highly distorted octahedral stereochemistry, whereas the latter is trigonal bipyramidal with an oxygen and a nitrogen atom apical and a pronounced lengthening of the axial Nd-N bond.

AB - Structures of the new complexes [La(Odpp)(3)(dig)]center dot 0.5dig (Odpp = 2,6-diphenylphenolate; dig = bis(2-methoxyethyl) ether - diglyme) and [Nd(Odpp)(3)(py)(2)]center dot 2py (py = pyridine), obtained by crystallization of the corresponding [Ln(Odpp)(3)(thf)(2)] complex from diglyme or pyridine contain six-coordinate and five-coordinate lanthanoid atoms respectively. In the former, two meridional sets of donor atoms, (O-3(dig) and O-3(Odpp)) are near normal to each other and in a highly distorted octahedral stereochemistry, whereas the latter is trigonal bipyramidal with an oxygen and a nitrogen atom apical and a pronounced lengthening of the axial Nd-N bond.

U2 - 10.1002/zaac.200600153

DO - 10.1002/zaac.200600153

M3 - Article

SN - 0044-2313

VL - 632

SP - 1986

EP - 1988

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 12-13

ER -

Deacon GB, Feng T, Junk PC, Skelton B, White A. X-ray Crystal Structure Characterization of Two Mononuclear Low Coordinate Lanthanoid Aryloxides, [La(Odpp)3(dig)]·0.5dig and [Nd(Odpp)3(py)2]·2py, (HOdpp = 2,6-diphenylphenol, dig = bis(2-methoxyethyl) ether, py = pyridine). Zeitschrift fur Anorganische und Allgemeine Chemie. 2006;632(12-13):1986-1988. doi: 10.1002/zaac.200600153