Titanocene dichloride route to a tetranuclear oxo-bridged monocyclopentadienyl titanium(IV) calix[4]arene complex

A.J. Petrella, N.K. Roberts, Colin Raston, M. Thornton-Pett, R.N. Lamb

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Lithiation of p-Bu-t-calix[4] arene followed by reaction with titanocene dichloride affords a novel tetranuclear titanium(IV) monocyclopentadienyl complex, wherein a single calix[4] arene in a cone conformation provides O-phenoxy coordination to four titanium atoms, with additional mu-oxo bridging between titanium centres in an eight membered ring.
Original languageEnglish
Pages (from-to)1238-1239
JournalChemical Communications
Volume11
DOIs
Publication statusPublished - 2003

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