TY - JOUR
T1 - Titanium(IV) imido complexes of 1,3,5-trialkyl-1,3,5-triazacyclohexanes
AU - Baker, Murray
AU - Palermo, M.C.
AU - Skelton, Brian
AU - White, Allan
PY - 1999
Y1 - 1999
N2 - Reactions of the imido complex Ti(NBut)Cl-2(py)(3) (py = pyridine) with 1,3,5-trialkyl-1,3,5-triazacyclohexanes (R(3)tach) produce the corresponding imido complexes TiCl2(NBut)(R(3)tach) (R = Et, Bu-t). The new complexes have been characterized by n.m.r. spectroscopy and, for the R = Bu-t case, by X-ray diffraction studies. The absence of a C-3 upsilon axis of symmetry for the new complexes allowed complete and unequivocal assignment of their H-1 n.m.r. spectra by consideration of proton-proton coupling and nuclear Overhauser erects.
AB - Reactions of the imido complex Ti(NBut)Cl-2(py)(3) (py = pyridine) with 1,3,5-trialkyl-1,3,5-triazacyclohexanes (R(3)tach) produce the corresponding imido complexes TiCl2(NBut)(R(3)tach) (R = Et, Bu-t). The new complexes have been characterized by n.m.r. spectroscopy and, for the R = Bu-t case, by X-ray diffraction studies. The absence of a C-3 upsilon axis of symmetry for the new complexes allowed complete and unequivocal assignment of their H-1 n.m.r. spectra by consideration of proton-proton coupling and nuclear Overhauser erects.
U2 - 10.1071/C98173
DO - 10.1071/C98173
M3 - Article
SN - 0004-9425
VL - 52
SP - 179
EP - 183
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - N/A
ER -