Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

G. Mislin, E. Graf, M.W. Hosseini, A. Bilyk, A.K. Hall, J.M. Harrowfield, Brian Skelton, Allan White

Research output: Contribution to journalArticle

111 Citations (Scopus)

Abstract

An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.
Original languageEnglish
Pages (from-to)373-374
JournalChemical Communications
VolumeN/A
Issue numberN/A
DOIs
Publication statusPublished - 1999

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