Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

G. Mislin; E. Graf; M.W. Hosseini; A. Bilyk; A.K. Hall; J.M. Harrowfield; Brian Skelton; Allan White

doi:10.1039/a809184f

Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

G. Mislin, E. Graf, M.W. Hosseini, A. Bilyk, A.K. Hall, J.M. Harrowfield, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

120 Citations (Scopus)

Abstract

An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.

Original language	English
Pages (from-to)	373-374
Journal	Chemical Communications
Volume	N/A
Issue number	N/A
DOIs	https://doi.org/10.1039/a809184f
Publication status	Published - 1999

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10.1039/a809184f

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title = "Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square",

abstract = "An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.",

author = "G. Mislin and E. Graf and M.W. Hosseini and A. Bilyk and A.K. Hall and J.M. Harrowfield and Brian Skelton and Allan White",

year = "1999",

doi = "10.1039/a809184f",

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pages = "373--374",

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T1 - Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

AU - Mislin, G.

AU - Graf, E.

AU - Hosseini, M.W.

AU - Bilyk, A.

AU - Hall, A.K.

AU - Harrowfield, J.M.

AU - Skelton, Brian

AU - White, Allan

PY - 1999

Y1 - 1999

N2 - An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.

AB - An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.

U2 - 10.1039/a809184f

DO - 10.1039/a809184f

M3 - Article

SN - 1359-7345

VL - N/A

SP - 373

EP - 374

JO - Chemical Communications

JF - Chemical Communications

IS - N/A

ER -

Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

Abstract

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