Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions

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Abstract

© 2015 Elsevier B.V. All rights reserved. Pitzer equations are widely employed to correlate and predict the volumetric properties of aqueous electrolyte solutions over broad ranges of pressure and temperature. However, the currently-used pressure and temperature terms are empirical and tend to violate known thermodynamic behaviour. Three functional constraints have been identified that overcome this problem.
Original languageEnglish
Pages (from-to)90-92
JournalTalanta
Volume144
DOIs
Publication statusPublished - 2015

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