The trans-[py2AlCl4]- ('py' = pyridine) Anion, Structurally Characterized in Two Pyridinium Salts

P.C. Junk; Colin Raston; Brian Skelton; Allan White

doi:10.1071/CH03206

The trans-[py2AlCl4]- ('py' = pyridine) Anion, Structurally Characterized in Two Pyridinium Salts

P.C. Junk, Colin Raston, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Salts of the trans-[py2AlCl4]– anion have been structurally characterized by ‘low’-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HCl · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HCl · 7py {=(pyH)3[(py)2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6–n)](n–3)± with ‘octahedral’ six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.

Original language	English
Pages (from-to)	503-506
Journal	Australian Journal of Chemistry
Volume	57
Issue number	5
DOIs	https://doi.org/10.1071/CH03206
Publication status	Published - 2004

Access to Document

10.1071/CH03206

Cite this

@article{8403c64d0395450c93a218cf2a330495,

title = "The trans-[py2AlCl4]- ('py' = pyridine) Anion, Structurally Characterized in Two Pyridinium Salts",

abstract = "Salts of the trans-[py2AlCl4]– anion have been structurally characterized by {\textquoteleft}low{\textquoteright}-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HCl · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HCl · 7py {=(pyH)3[(py)2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6–n)](n–3)± with {\textquoteleft}octahedral{\textquoteright} six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.",

author = "P.C. Junk and Colin Raston and Brian Skelton and Allan White",

year = "2004",

doi = "10.1071/CH03206",

language = "English",

volume = "57",

pages = "503--506",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "5",

}

TY - JOUR

T1 - The trans-[py2AlCl4]- ('py' = pyridine) Anion, Structurally Characterized in Two Pyridinium Salts

AU - Junk, P.C.

AU - Raston, Colin

AU - Skelton, Brian

AU - White, Allan

PY - 2004

Y1 - 2004

N2 - Salts of the trans-[py2AlCl4]– anion have been structurally characterized by ‘low’-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HCl · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HCl · 7py {=(pyH)3[(py)2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6–n)](n–3)± with ‘octahedral’ six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.

AB - Salts of the trans-[py2AlCl4]– anion have been structurally characterized by ‘low’-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HCl · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HCl · 7py {=(pyH)3[(py)2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6–n)](n–3)± with ‘octahedral’ six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.

U2 - 10.1071/CH03206

DO - 10.1071/CH03206

M3 - Article

SN - 0004-9425

VL - 57

SP - 503

EP - 506

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 5

ER -

The trans-[py2AlCl4]- ('py' = pyridine) Anion, Structurally Characterized in Two Pyridinium Salts

Abstract

Access to Document

Fingerprint

Cite this