The synthesis of various 1,6-disulfide-B ridged D-hexopyranoses

E.D. Goddard-Borger; Robert Stick

doi:10.1071/CH04277

The synthesis of various 1,6-disulfide-B ridged D-hexopyranoses

E.D. Goddard-Borger, Robert Stick

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

1,6-Disulfide-bridged derivatives have been prepared for D-gluco-, D-manno-, D-allo-, D-galacto-, and D-talopyranose, in the main by the nucleophilic attack of a C6 thiolate onto an anomeric thiosulfonate. The D-gluco disulfide, 'angyalosan', was successfully oxidized to a single thiosulfinate.

Original language	English
Pages (from-to)	188-198
Journal	Australian Journal of Chemistry
Volume	58
Issue number	3
DOIs	https://doi.org/10.1071/CH04277
Publication status	Published - 2005

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title = "The synthesis of various 1,6-disulfide-B ridged D-hexopyranoses",

abstract = "1,6-Disulfide-bridged derivatives have been prepared for D-gluco-, D-manno-, D-allo-, D-galacto-, and D-talopyranose, in the main by the nucleophilic attack of a C6 thiolate onto an anomeric thiosulfonate. The D-gluco disulfide, 'angyalosan', was successfully oxidized to a single thiosulfinate.",

author = "E.D. Goddard-Borger and Robert Stick",

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AU - Goddard-Borger, E.D.

AU - Stick, Robert

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N2 - 1,6-Disulfide-bridged derivatives have been prepared for D-gluco-, D-manno-, D-allo-, D-galacto-, and D-talopyranose, in the main by the nucleophilic attack of a C6 thiolate onto an anomeric thiosulfonate. The D-gluco disulfide, 'angyalosan', was successfully oxidized to a single thiosulfinate.

AB - 1,6-Disulfide-bridged derivatives have been prepared for D-gluco-, D-manno-, D-allo-, D-galacto-, and D-talopyranose, in the main by the nucleophilic attack of a C6 thiolate onto an anomeric thiosulfonate. The D-gluco disulfide, 'angyalosan', was successfully oxidized to a single thiosulfinate.

U2 - 10.1071/CH04277

DO - 10.1071/CH04277

M3 - Article

SN - 0004-9425

VL - 58

SP - 188

EP - 198

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 3

ER -

The synthesis of various 1,6-disulfide-B ridged D-hexopyranoses

Abstract

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