The direct decomposition of nitric oxide over fe/CNOs (CNOs: Carbon Nano Onions)

J. Cui; Lizhen Gao; S. Yan; W. Zhang; Y. Li

doi:10.1080/15533174.2013.818031

The direct decomposition of nitric oxide over fe/CNOs (CNOs: Carbon Nano Onions)

J. Cui, Lizhen Gao, S. Yan, W. Zhang, Y. Li

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Copyright © Taylor & Francis Group, LLC. The decomposition of NO was studied over carbon nano onions (CNOs) supported Fe catalyst made in a facility of spinning disc process (SDP). At the temperature of 500°C, 83% NO was decomposed to N2 with 93% of selectivity (N2 formation rate: 3.44 mol N2·s^-1·gcatalyst^-1). The rest are the by-products of NO2 and N2O. X-ray diffraction study demonstrated that the iron carbide was generated in the catalyst. Thermogravimetric analysis indicated that CNOs were stable below 600°C under air atmosphere. In situ diffuse reflectance infrared Fourier transformation spectroscopy study detected the NO2 and N2O2 species during NO adsorption.

Original language	English
Pages (from-to)	158-163
Journal	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume	45
Issue number	2
DOIs	https://doi.org/10.1080/15533174.2013.818031
Publication status	Published - 2015

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title = "The direct decomposition of nitric oxide over fe/CNOs (CNOs: Carbon Nano Onions)",

abstract = "Copyright {\textcopyright} Taylor & Francis Group, LLC. The decomposition of NO was studied over carbon nano onions (CNOs) supported Fe catalyst made in a facility of spinning disc process (SDP). At the temperature of 500°C, 83% NO was decomposed to N2 with 93% of selectivity (N2 formation rate: 3.44 mol N2·s-1·gcatalyst-1). The rest are the by-products of NO2 and N2O. X-ray diffraction study demonstrated that the iron carbide was generated in the catalyst. Thermogravimetric analysis indicated that CNOs were stable below 600°C under air atmosphere. In situ diffuse reflectance infrared Fourier transformation spectroscopy study detected the NO2 and N2O2 species during NO adsorption.",

author = "J. Cui and Lizhen Gao and S. Yan and W. Zhang and Y. Li",

year = "2015",

doi = "10.1080/15533174.2013.818031",

language = "English",

volume = "45",

pages = "158--163",

journal = "Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry",

issn = "1553-3174",

publisher = "Taylor & Francis",

number = "2",

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TY - JOUR

T1 - The direct decomposition of nitric oxide over fe/CNOs (CNOs: Carbon Nano Onions)

AU - Cui, J.

AU - Gao, Lizhen

AU - Yan, S.

AU - Zhang, W.

AU - Li, Y.

PY - 2015

Y1 - 2015

N2 - Copyright © Taylor & Francis Group, LLC. The decomposition of NO was studied over carbon nano onions (CNOs) supported Fe catalyst made in a facility of spinning disc process (SDP). At the temperature of 500°C, 83% NO was decomposed to N2 with 93% of selectivity (N2 formation rate: 3.44 mol N2·s-1·gcatalyst-1). The rest are the by-products of NO2 and N2O. X-ray diffraction study demonstrated that the iron carbide was generated in the catalyst. Thermogravimetric analysis indicated that CNOs were stable below 600°C under air atmosphere. In situ diffuse reflectance infrared Fourier transformation spectroscopy study detected the NO2 and N2O2 species during NO adsorption.

AB - Copyright © Taylor & Francis Group, LLC. The decomposition of NO was studied over carbon nano onions (CNOs) supported Fe catalyst made in a facility of spinning disc process (SDP). At the temperature of 500°C, 83% NO was decomposed to N2 with 93% of selectivity (N2 formation rate: 3.44 mol N2·s-1·gcatalyst-1). The rest are the by-products of NO2 and N2O. X-ray diffraction study demonstrated that the iron carbide was generated in the catalyst. Thermogravimetric analysis indicated that CNOs were stable below 600°C under air atmosphere. In situ diffuse reflectance infrared Fourier transformation spectroscopy study detected the NO2 and N2O2 species during NO adsorption.

U2 - 10.1080/15533174.2013.818031

DO - 10.1080/15533174.2013.818031

M3 - Article

VL - 45

SP - 158

EP - 163

JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

SN - 1553-3174

IS - 2

ER -

The direct decomposition of nitric oxide over fe/CNOs (CNOs: Carbon Nano Onions)

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