The Bis-{Co2(µ-dppm)(CO)4} Adduct of Dimethyl hex-3-en-1,5-diyne-1,6-dicarboxylate

M.I. Bruce, Brian Skelton, Allan White, N.N. Zaitseva

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The synthesis and structural characterization of a bis-dicobalt derivative of dimethyl hex-3-en-1,5-diyne-1,6-dicarboxylate, [{Co(0)2(mu-dppm)(CO)(4)}(2)(mu:mu-MeO2CC2CH=CHC2CO2Me)]center dot 2CHCl(3) (1) is described, permitting, in the context of previous related studies, comparison of the effects of progressive substitution of the ethene hydrogen atoms by C C center dot SiMe3 groupings.
Original languageEnglish
Pages (from-to)1102-1105
JournalZeitschrift fuer Anorganische und Allgemeine Chemie
Volume634
DOIs
Publication statusPublished - 2008

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