Tetraiodoallene, I2C≤C≤CI2 - The missing link between I2C≤CI2 and I2C≤C≤C≤CI2 - And the oxidation product, 2,2-diiodoacrylicacid, I2C≤CH(CO2H)

Michael I. Bruce, Nicholas J. Head, Brian W. Skelton, Mark A. Spackman, Allan H. White

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The X-ray structure of tetraiodoallene is reported. On standing, atmospheric hydrolysis converts this compound into 2,2-diiodoacrylic acid, for which a structure has also been determined. Energy framework diagrams have been constructed for the two compounds.

Original languageEnglish
Pages (from-to)70-73
Number of pages4
JournalAustralian Journal of Chemistry
Volume71
Issue number1
DOIs
Publication statusPublished - 1 Jan 2018

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Hydrolysis
X rays
Oxidation
Acids

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title = "Tetraiodoallene, I2C≤C≤CI2 - The missing link between I2C≤CI2 and I2C≤C≤C≤CI2 - And the oxidation product, 2,2-diiodoacrylicacid, I2C≤CH(CO2H)",
abstract = "The X-ray structure of tetraiodoallene is reported. On standing, atmospheric hydrolysis converts this compound into 2,2-diiodoacrylic acid, for which a structure has also been determined. Energy framework diagrams have been constructed for the two compounds.",
author = "Bruce, {Michael I.} and Head, {Nicholas J.} and Skelton, {Brian W.} and Spackman, {Mark A.} and White, {Allan H.}",
year = "2018",
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doi = "10.1071/CH17348",
language = "English",
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pages = "70--73",
journal = "Australian Journal of Chemistry:an international journal for chemical science",
issn = "0004-9425",
publisher = "CSIRO Publishing",
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Tetraiodoallene, I2C≤C≤CI2 - The missing link between I2C≤CI2 and I2C≤C≤C≤CI2 - And the oxidation product, 2,2-diiodoacrylicacid, I2C≤CH(CO2H). / Bruce, Michael I.; Head, Nicholas J.; Skelton, Brian W.; Spackman, Mark A.; White, Allan H.

In: Australian Journal of Chemistry, Vol. 71, No. 1, 01.01.2018, p. 70-73.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Tetraiodoallene, I2C≤C≤CI2 - The missing link between I2C≤CI2 and I2C≤C≤C≤CI2 - And the oxidation product, 2,2-diiodoacrylicacid, I2C≤CH(CO2H)

AU - Bruce, Michael I.

AU - Head, Nicholas J.

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AU - Spackman, Mark A.

AU - White, Allan H.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The X-ray structure of tetraiodoallene is reported. On standing, atmospheric hydrolysis converts this compound into 2,2-diiodoacrylic acid, for which a structure has also been determined. Energy framework diagrams have been constructed for the two compounds.

AB - The X-ray structure of tetraiodoallene is reported. On standing, atmospheric hydrolysis converts this compound into 2,2-diiodoacrylic acid, for which a structure has also been determined. Energy framework diagrams have been constructed for the two compounds.

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U2 - 10.1071/CH17348

DO - 10.1071/CH17348

M3 - Article

VL - 71

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JO - Australian Journal of Chemistry:an international journal for chemical science

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SN - 0004-9425

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