Tetraiodoallene, I2C≤C≤CI2 - The missing link between I2C≤CI2 and I2C≤C≤C≤CI2 - And the oxidation product, 2,2-diiodoacrylicacid, I2C≤CH(CO2H)

Michael I. Bruce; Nicholas J. Head; Brian W. Skelton; Mark A. Spackman; Allan H. White

doi:10.1071/CH17348

Tetraiodoallene, I₂C≤C≤CI₂ - The missing link between I₂C≤CI₂ and I₂C≤C≤C≤CI₂ - And the oxidation product, 2,2-diiodoacrylicacid, I₂C≤CH(CO₂H)

Michael I. Bruce, Nicholas J. Head, Brian W. Skelton, Mark A. Spackman, Allan H. White

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The X-ray structure of tetraiodoallene is reported. On standing, atmospheric hydrolysis converts this compound into 2,2-diiodoacrylic acid, for which a structure has also been determined. Energy framework diagrams have been constructed for the two compounds.

Original language	English
Pages (from-to)	70-73
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	71
Issue number	1
DOIs	https://doi.org/10.1071/CH17348
Publication status	Published - 1 Jan 2018

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title = "Tetraiodoallene, I2C≤C≤CI2 - The missing link between I2C≤CI2 and I2C≤C≤C≤CI2 - And the oxidation product, 2,2-diiodoacrylicacid, I2C≤CH(CO2H)",

abstract = "The X-ray structure of tetraiodoallene is reported. On standing, atmospheric hydrolysis converts this compound into 2,2-diiodoacrylic acid, for which a structure has also been determined. Energy framework diagrams have been constructed for the two compounds.",

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AU - Bruce, Michael I.

AU - Head, Nicholas J.

AU - Skelton, Brian W.

AU - Spackman, Mark A.

AU - White, Allan H.

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AB - The X-ray structure of tetraiodoallene is reported. On standing, atmospheric hydrolysis converts this compound into 2,2-diiodoacrylic acid, for which a structure has also been determined. Energy framework diagrams have been constructed for the two compounds.

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JF - Australian Journal of Chemistry

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Tetraiodoallene, I₂C≤C≤CI₂ - The missing link between I₂C≤CI₂ and I₂C≤C≤C≤CI₂ - And the oxidation product, 2,2-diiodoacrylicacid, I₂C≤CH(CO₂H)

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