Synthesis, photoluminescence, catalysis and multilayer film assembly of an ethynylpyridine platinum compound

X. Li; M.-Q. Zha; S.-Y. Gao; Paul Low; Y.-Z. Wu; N. Gan; R. Cao

doi:10.1039/c0ce00382d

Synthesis, photoluminescence, catalysis and multilayer film assembly of an ethynylpyridine platinum compound

X. Li, M.-Q. Zha, S.-Y. Gao, Paul Low, Y.-Z. Wu, N. Gan, R. Cao

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

An alkynyl platinum(II) compound of [Pt(C[triple bond, length as m-dash]CPy)2(dppe)] (1) was prepared by reaction of [PtCl2(dppe)] and 4-ethynylpyridine hydrochloride in the presence of base and CuI (dppe = 1,2-bis(diphenylphosphino)ethane). Single crystal X-ray diffraction analysis reveals that compound 1 crystallizes in a monoclinic system and Cc space group with a = 17.8507(7), b = 21.4219(7), c = 9.0526(5) Å, β = 108.98(2)°. Thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), UV-vis spectra, photoluminescence, and catalysis properties of 1 are discussed. The multilayer films formed with ruthenium trichloride by a layer-by-layer self-assembly method were characterized by UV-vis spectra, atomic force microscopy (AFM) images and cyclic voltammograms (CV).

Original language	English
Pages (from-to)	920-926
Journal	CrystEngComm
Volume	13
Issue number	3
Early online date	21 Oct 2010
DOIs	https://doi.org/10.1039/c0ce00382d
Publication status	Published - 7 Feb 2011

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title = "Synthesis, photoluminescence, catalysis and multilayer film assembly of an ethynylpyridine platinum compound",

abstract = "An alkynyl platinum(II) compound of [Pt(C[triple bond, length as m-dash]CPy)2(dppe)] (1) was prepared by reaction of [PtCl2(dppe)] and 4-ethynylpyridine hydrochloride in the presence of base and CuI (dppe = 1,2-bis(diphenylphosphino)ethane). Single crystal X-ray diffraction analysis reveals that compound 1 crystallizes in a monoclinic system and Cc space group with a = 17.8507(7), b = 21.4219(7), c = 9.0526(5) {\AA}, β = 108.98(2)°. Thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), UV-vis spectra, photoluminescence, and catalysis properties of 1 are discussed. The multilayer films formed with ruthenium trichloride by a layer-by-layer self-assembly method were characterized by UV-vis spectra, atomic force microscopy (AFM) images and cyclic voltammograms (CV).",

author = "X. Li and M.-Q. Zha and S.-Y. Gao and Paul Low and Y.-Z. Wu and N. Gan and R. Cao",

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T1 - Synthesis, photoluminescence, catalysis and multilayer film assembly of an ethynylpyridine platinum compound

AU - Li, X.

AU - Zha, M.-Q.

AU - Gao, S.-Y.

AU - Low, Paul

AU - Wu, Y.-Z.

AU - Gan, N.

AU - Cao, R.

PY - 2011/2/7

Y1 - 2011/2/7

N2 - An alkynyl platinum(II) compound of [Pt(C[triple bond, length as m-dash]CPy)2(dppe)] (1) was prepared by reaction of [PtCl2(dppe)] and 4-ethynylpyridine hydrochloride in the presence of base and CuI (dppe = 1,2-bis(diphenylphosphino)ethane). Single crystal X-ray diffraction analysis reveals that compound 1 crystallizes in a monoclinic system and Cc space group with a = 17.8507(7), b = 21.4219(7), c = 9.0526(5) Å, β = 108.98(2)°. Thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), UV-vis spectra, photoluminescence, and catalysis properties of 1 are discussed. The multilayer films formed with ruthenium trichloride by a layer-by-layer self-assembly method were characterized by UV-vis spectra, atomic force microscopy (AFM) images and cyclic voltammograms (CV).

AB - An alkynyl platinum(II) compound of [Pt(C[triple bond, length as m-dash]CPy)2(dppe)] (1) was prepared by reaction of [PtCl2(dppe)] and 4-ethynylpyridine hydrochloride in the presence of base and CuI (dppe = 1,2-bis(diphenylphosphino)ethane). Single crystal X-ray diffraction analysis reveals that compound 1 crystallizes in a monoclinic system and Cc space group with a = 17.8507(7), b = 21.4219(7), c = 9.0526(5) Å, β = 108.98(2)°. Thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), UV-vis spectra, photoluminescence, and catalysis properties of 1 are discussed. The multilayer films formed with ruthenium trichloride by a layer-by-layer self-assembly method were characterized by UV-vis spectra, atomic force microscopy (AFM) images and cyclic voltammograms (CV).

U2 - 10.1039/c0ce00382d

DO - 10.1039/c0ce00382d

M3 - Article

SN - 1466-8033

VL - 13

SP - 920

EP - 926

JO - CrystEngComm

JF - CrystEngComm

IS - 3

ER -

Synthesis, photoluminescence, catalysis and multilayer film assembly of an ethynylpyridine platinum compound

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