Synthesis of novel amidoxime-linked pseudodisaccharides

Iain A. S. Smellie, Stephen A. Moggach, R. Michael Paton

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Abstract

Disaccharide analogues containing amidoxime interglycosidic linkages have been synthesised by nucleophilic addition of aminomethylene pyranoses to pyranosyl nitrile oxides, generated by dehydrochlorination of the corresponding hydroximoyl chlorides. The structure of the C-xylopyranosyl-N-galactopyranosyl amidoxime 1 was established by X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)95-97
Number of pages3
JournalTetrahedron Letters
Volume52
Issue number1
DOIs
Publication statusPublished - 5 Jan 2011
Externally publishedYes

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