Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H]

Xunjin Zhu; Richard M. Ward; David Albesa-Jove; Judith A. K. Howard; Laurent Porres; Andrew Beeby; Paul J. Low; Wai-Kwok Wong; Todd B. Marder

doi:10.1016/j.ica.2005.11.030

Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H]

Xunjin Zhu, Richard M. Ward, David Albesa-Jove, Judith A. K. Howard, Laurent Porres, Andrew Beeby, Paul J. Low, Wai-Kwok Wong, Todd B. Marder

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Terminal alkynes (R-C C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4 C C-)-C6H4) react with [Rh(PMe3)(4)Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer, trans-[(PMe3)(3)Rh(C CR)(2)H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	2859-2863
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	359
Issue number	9
DOIs	https://doi.org/10.1016/j.ica.2005.11.030
Publication status	Published - 1 Jun 2006
Externally published	Yes

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@article{5d8d891b977145ee948d388007344657,

title = "Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H]",

abstract = "Terminal alkynes (R-C C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4 C C-)-C6H4) react with [Rh(PMe3)(4)Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer, trans-[(PMe3)(3)Rh(C CR)(2)H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative. (c) 2005 Elsevier B.V. All rights reserved.",

keywords = "acetylide, alkynyl, luminescent, hydride, crystal structure, METAL ACETYLIDE CATALYSTS, LIQUID-CRYSTALLINE MATERIALS, NONLINEAR-OPTICAL PROPERTIES, ALL-CARBON LIGANDS, TRANSITION-METALS, ELECTRONIC-STRUCTURE, MOLECULAR-STRUCTURE, ORGANOMETALLIC DENDRIMERS, RUTHENIUM COMPLEXES, ALKYNYL COMPLEXES",

author = "Xunjin Zhu and Ward, \{Richard M.\} and David Albesa-Jove and Howard, \{Judith A. K.\} and Laurent Porres and Andrew Beeby and Low, \{Paul J.\} and Wai-Kwok Wong and Marder, \{Todd B.\}",

year = "2006",

month = jun,

day = "1",

doi = "10.1016/j.ica.2005.11.030",

language = "English",

volume = "359",

pages = "2859--2863",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "9",

}

TY - JOUR

T1 - Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes

T2 - Structure of mer,trans-[(PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H]

AU - Zhu, Xunjin

AU - Ward, Richard M.

AU - Albesa-Jove, David

AU - Howard, Judith A. K.

AU - Porres, Laurent

AU - Beeby, Andrew

AU - Low, Paul J.

AU - Wong, Wai-Kwok

AU - Marder, Todd B.

PY - 2006/6/1

Y1 - 2006/6/1

N2 - Terminal alkynes (R-C C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4 C C-)-C6H4) react with [Rh(PMe3)(4)Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer, trans-[(PMe3)(3)Rh(C CR)(2)H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative. (c) 2005 Elsevier B.V. All rights reserved.

AB - Terminal alkynes (R-C C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4 C C-)-C6H4) react with [Rh(PMe3)(4)Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer, trans-[(PMe3)(3)Rh(C CR)(2)H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative. (c) 2005 Elsevier B.V. All rights reserved.

KW - acetylide

KW - alkynyl

KW - luminescent

KW - hydride

KW - crystal structure

KW - METAL ACETYLIDE CATALYSTS

KW - LIQUID-CRYSTALLINE MATERIALS

KW - NONLINEAR-OPTICAL PROPERTIES

KW - ALL-CARBON LIGANDS

KW - TRANSITION-METALS

KW - ELECTRONIC-STRUCTURE

KW - MOLECULAR-STRUCTURE

KW - ORGANOMETALLIC DENDRIMERS

KW - RUTHENIUM COMPLEXES

KW - ALKYNYL COMPLEXES

UR - https://www.scopus.com/pages/publications/33646534837

U2 - 10.1016/j.ica.2005.11.030

DO - 10.1016/j.ica.2005.11.030

M3 - Article

SN - 0020-1693

VL - 359

SP - 2859

EP - 2863

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 9

ER -

Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H]

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