@article{5d8d891b977145ee948d388007344657,
title = "Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H]",
abstract = "Terminal alkynes (R-C C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4 C C-)-C6H4) react with [Rh(PMe3)(4)Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer, trans-[(PMe3)(3)Rh(C CR)(2)H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative. (c) 2005 Elsevier B.V. All rights reserved.",
keywords = "acetylide, alkynyl, luminescent, hydride, crystal structure, METAL ACETYLIDE CATALYSTS, LIQUID-CRYSTALLINE MATERIALS, NONLINEAR-OPTICAL PROPERTIES, ALL-CARBON LIGANDS, TRANSITION-METALS, ELECTRONIC-STRUCTURE, MOLECULAR-STRUCTURE, ORGANOMETALLIC DENDRIMERS, RUTHENIUM COMPLEXES, ALKYNYL COMPLEXES",
author = "Xunjin Zhu and Ward, {Richard M.} and David Albesa-Jove and Howard, {Judith A. K.} and Laurent Porres and Andrew Beeby and Low, {Paul J.} and Wai-Kwok Wong and Marder, {Todd B.}",
year = "2006",
month = jun,
day = "1",
doi = "10.1016/j.ica.2005.11.030",
language = "English",
volume = "359",
pages = "2859--2863",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier Science & Technology",
number = "9",
}