TY - JOUR
T1 - Synthesis of a new five-coordinate ternary copper (II) complex
T2 - crystal structure and spectral studies
AU - Rezvani, A.R.
AU - Janani, H.
AU - Rostami Charati, Faramarz
AU - Skelton, Brian Warwick
PY - 2017
Y1 - 2017
N2 - A new ternary complex of benzhydrazide-phenanthroline-H2O ligands with copper (II) was synthesized and characterized by elemental analysis, infrared spectroscopy and UV-Vis electronic absorption spectroscopy. The crystal and molecular structure of [Cu(BH)(Phen)(H2O) ]2NO3.1.5 H2O was determined by the single crystal diffraction method which confirmed that the complex has square pyramidal geometry and contains a bidentate heterocyclic ligand on one side and a bidentate benzhydrazide (BH) ligand on the other side. This coordination takes place through the nitrogen and oxygen atoms from benzhydrazide and two nitrogen atoms from 1,10-phenanthroline. The apical position is occupied by an oxygen atom from a water molecule as a third ligand.
AB - A new ternary complex of benzhydrazide-phenanthroline-H2O ligands with copper (II) was synthesized and characterized by elemental analysis, infrared spectroscopy and UV-Vis electronic absorption spectroscopy. The crystal and molecular structure of [Cu(BH)(Phen)(H2O) ]2NO3.1.5 H2O was determined by the single crystal diffraction method which confirmed that the complex has square pyramidal geometry and contains a bidentate heterocyclic ligand on one side and a bidentate benzhydrazide (BH) ligand on the other side. This coordination takes place through the nitrogen and oxygen atoms from benzhydrazide and two nitrogen atoms from 1,10-phenanthroline. The apical position is occupied by an oxygen atom from a water molecule as a third ligand.
UR - https://www.scopus.com/pages/publications/85084840358
M3 - Article
SN - 0324-1130
VL - 49
SP - 74
EP - 78
JO - Bulgarian Chemical Communications
JF - Bulgarian Chemical Communications
IS - 1
ER -