Synthesis of a new five-coordinate ternary copper (II) complex: crystal structure and spectral studies

A.R. Rezvani, H. Janani, Faramarz Rostami Charati, Brian Warwick Skelton

Research output: Contribution to journalArticle

Abstract

A new ternary complex of benzhydrazide-phenanthroline-H2O ligands with copper (II) was synthesized and characterized by elemental analysis, infrared spectroscopy and UV-Vis electronic absorption spectroscopy. The crystal and molecular structure of [Cu(BH)(Phen)(H2O) ]2NO3.1.5 H2O was determined by the single crystal diffraction method which confirmed that the complex has square pyramidal geometry and contains a bidentate heterocyclic ligand on one side and a bidentate benzhydrazide (BH) ligand on the other side. This coordination takes place through the nitrogen and oxygen atoms from benzhydrazide and two nitrogen atoms from 1,10-phenanthroline. The apical position is occupied by an oxygen atom from a water molecule as a third ligand.
Original languageEnglish
Pages (from-to)74-78
Number of pages5
JournalBulgarian Chemical Communications
Volume49
Issue number1
Publication statusPublished - 2017

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