Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex

J. Wang; D.N. Stringer; M.G. Gardiner; Brian Skelton; Allan White

doi:10.1016/j.jorganchem.2004.09.016

Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex

J. Wang
, D.N. Stringer
, M.G. Gardiner
, Brian Skelton
, Allan White

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The synthesis of 2,5-bis{(diethyl-3'-indolyl)methyl} furan by the acid catalysed condensation of 2,5-bis(diethylhydroxymethyl)furan with indole is presented. Dilithium, disodium and dipotassium derivatives are prepared by the reaction of the bis(indole) with n-BuLi, NaH and K, respectively, in the presence of various Lewis bases. The X-ray structures of 2,5-bis{(diethyl-3'-indolyl)rnethyl} furan and the dilithiated derivative (as a polymeric tetrahydrofuran adduct) are reported. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	220-227
Journal	Journal of Organometallic Chemistry
Volume	690
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2004.09.016
Publication status	Published - 2005

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Wang, J., Stringer, D. N., Gardiner, M. G., Skelton, B., & White, A. (2005). Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex. Journal of Organometallic Chemistry, 690(1), 220-227. https://doi.org/10.1016/j.jorganchem.2004.09.016

Wang, J. ; Stringer, D.N. ; Gardiner, M.G. et al. / Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex. In: Journal of Organometallic Chemistry. 2005 ; Vol. 690, No. 1. pp. 220-227.

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title = "Synthesis of 2,5-bis\{(diethyl-3′-indolyl)methyl\}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis\{(diethyl-3′-indolyl)methyl\}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex",

abstract = "The synthesis of 2,5-bis\{(diethyl-3'-indolyl)methyl\} furan by the acid catalysed condensation of 2,5-bis(diethylhydroxymethyl)furan with indole is presented. Dilithium, disodium and dipotassium derivatives are prepared by the reaction of the bis(indole) with n-BuLi, NaH and K, respectively, in the presence of various Lewis bases. The X-ray structures of 2,5-bis\{(diethyl-3'-indolyl)rnethyl\} furan and the dilithiated derivative (as a polymeric tetrahydrofuran adduct) are reported. (C) 2004 Elsevier B.V. All rights reserved.",

author = "J. Wang and D.N. Stringer and M.G. Gardiner and Brian Skelton and Allan White",

year = "2005",

doi = "10.1016/j.jorganchem.2004.09.016",

language = "English",

volume = "690",

pages = "220--227",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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Wang, J, Stringer, DN, Gardiner, MG, Skelton, B & White, A 2005, 'Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex', Journal of Organometallic Chemistry, vol. 690, no. 1, pp. 220-227. https://doi.org/10.1016/j.jorganchem.2004.09.016

Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex. / Wang, J.; Stringer, D.N.; Gardiner, M.G. et al.
In: Journal of Organometallic Chemistry, Vol. 690, No. 1, 2005, p. 220-227.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex

AU - Wang, J.

AU - Stringer, D.N.

AU - Gardiner, M.G.

AU - Skelton, Brian

AU - White, Allan

PY - 2005

Y1 - 2005

N2 - The synthesis of 2,5-bis{(diethyl-3'-indolyl)methyl} furan by the acid catalysed condensation of 2,5-bis(diethylhydroxymethyl)furan with indole is presented. Dilithium, disodium and dipotassium derivatives are prepared by the reaction of the bis(indole) with n-BuLi, NaH and K, respectively, in the presence of various Lewis bases. The X-ray structures of 2,5-bis{(diethyl-3'-indolyl)rnethyl} furan and the dilithiated derivative (as a polymeric tetrahydrofuran adduct) are reported. (C) 2004 Elsevier B.V. All rights reserved.

AB - The synthesis of 2,5-bis{(diethyl-3'-indolyl)methyl} furan by the acid catalysed condensation of 2,5-bis(diethylhydroxymethyl)furan with indole is presented. Dilithium, disodium and dipotassium derivatives are prepared by the reaction of the bis(indole) with n-BuLi, NaH and K, respectively, in the presence of various Lewis bases. The X-ray structures of 2,5-bis{(diethyl-3'-indolyl)rnethyl} furan and the dilithiated derivative (as a polymeric tetrahydrofuran adduct) are reported. (C) 2004 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.jorganchem.2004.09.016

DO - 10.1016/j.jorganchem.2004.09.016

M3 - Article

SN - 0022-328X

VL - 690

SP - 220

EP - 227

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Wang J, Stringer DN, Gardiner MG, Skelton B, White A. Synthesis of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and its N,N′-dimetallated complexes (lithium, sodium and potassium): X-ray crystal structures of 2,5-bis{(diethyl-3′-indolyl)methyl}furan and the polymeric tetrahydrofuran adduct of the dilithiated complex. Journal of Organometallic Chemistry. 2005;690(1):220-227. doi: 10.1016/j.jorganchem.2004.09.016