Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]

M.P. Batten, A.J. Canty, K.J. Cavell, Brian Skelton, Allan White

Research output: Contribution to journalArticle

Abstract

The complexes [Mo(CO)(4)(L-2-N,N')] [L-2 = 1-methylimidazol -2-yl (pyridin-2-yl) met ban one and 1-benzylimidazol-2-yl(1-phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.
Original languageEnglish
Pages (from-to)876-878
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume632
Issue number5
DOIs
Publication statusPublished - 2006

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