Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]

M.P. Batten; A.J. Canty; K.J. Cavell; Brian Skelton; Allan White

doi:10.1002/zaac.200500531

Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]

M.P. Batten, A.J. Canty, K.J. Cavell, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The complexes [Mo(CO)(4)(L-2-N,N')] [L-2 = 1-methylimidazol -2-yl (pyridin-2-yl) met ban one and 1-benzylimidazol-2-yl(1-phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

Original language	English
Pages (from-to)	876-878
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	632
Issue number	5
DOIs	https://doi.org/10.1002/zaac.200500531
Publication status	Published - 2006

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Batten, M. P., Canty, A. J., Cavell, K. J., Skelton, B., & White, A. (2006). Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]. Zeitschrift fur Anorganische und Allgemeine Chemie, 632(5), 876-878. https://doi.org/10.1002/zaac.200500531

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title = "Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]",

abstract = "The complexes [Mo(CO)(4)(L-2-N,N')] [L-2 = 1-methylimidazol -2-yl (pyridin-2-yl) met ban one and 1-benzylimidazol-2-yl(1-phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.",

author = "M.P. Batten and A.J. Canty and K.J. Cavell and Brian Skelton and Allan White",

year = "2006",

doi = "10.1002/zaac.200500531",

language = "English",

volume = "632",

pages = "876--878",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

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number = "5",

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Batten, MP, Canty, AJ, Cavell, KJ, Skelton, B & White, A 2006, 'Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 632, no. 5, pp. 876-878. https://doi.org/10.1002/zaac.200500531

Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]. / Batten, M.P.; Canty, A.J.; Cavell, K.J. et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 632, No. 5, 2006, p. 876-878.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]

AU - Batten, M.P.

AU - Canty, A.J.

AU - Cavell, K.J.

AU - Skelton, Brian

AU - White, Allan

PY - 2006

Y1 - 2006

N2 - The complexes [Mo(CO)(4)(L-2-N,N')] [L-2 = 1-methylimidazol -2-yl (pyridin-2-yl) met ban one and 1-benzylimidazol-2-yl(1-phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

AB - The complexes [Mo(CO)(4)(L-2-N,N')] [L-2 = 1-methylimidazol -2-yl (pyridin-2-yl) met ban one and 1-benzylimidazol-2-yl(1-phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

U2 - 10.1002/zaac.200500531

DO - 10.1002/zaac.200500531

M3 - Article

SN - 0044-2313

VL - 632

SP - 876

EP - 878

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 5

ER -

Batten MP, Canty AJ, Cavell KJ, Skelton B, White A. Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N, N′)]. Zeitschrift fur Anorganische und Allgemeine Chemie. 2006;632(5):876-878. doi: 10.1002/zaac.200500531