TY - JOUR
T1 - Synthesis and Structure of the Binuclear 1:1 Silver(I) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex
AU - Bin Othman, A.H.
AU - Effendy, Effendy
AU - Skelton, Brian
AU - White, Allan
PY - 2003
Y1 - 2003
N2 - A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.
AB - A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.
UR - https://www.scopus.com/pages/publications/0043268798
U2 - 10.1071/CH02135
DO - 10.1071/CH02135
M3 - Article
SN - 0004-9425
VL - 56
SP - 719
EP - 721
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 7
ER -