Synthesis and Structure of the Binuclear 1:1 Silver(I) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex

A.H. Bin Othman; Effendy Effendy; Brian Skelton; Allan White

doi:10.1071/CH02135

Synthesis and Structure of the Binuclear 1:1 Silver(I) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex

A.H. Bin Othman, Effendy Effendy, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

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Abstract

A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.

Original language	English
Pages (from-to)	719-721
Journal	Australian Journal of Chemistry
Volume	56
Issue number	7
DOIs	https://doi.org/10.1071/CH02135
Publication status	Published - 2003

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10.1071/CH02135

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title = "Synthesis and Structure of the Binuclear 1:1 Silver(I) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex",

abstract = "A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.",

author = "{Bin Othman}, A.H. and Effendy Effendy and Brian Skelton and Allan White",

year = "2003",

doi = "10.1071/CH02135",

language = "English",

volume = "56",

pages = "719--721",

journal = "Australian Journal of Chemistry:an international journal for chemical science",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "7",

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TY - JOUR

T1 - Synthesis and Structure of the Binuclear 1:1 Silver(I) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex

AU - Bin Othman, A.H.

AU - Effendy, Effendy

AU - Skelton, Brian

AU - White, Allan

PY - 2003

Y1 - 2003

N2 - A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.

AB - A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.

U2 - 10.1071/CH02135

DO - 10.1071/CH02135

M3 - Article

VL - 56

SP - 719

EP - 721

JO - Australian Journal of Chemistry:an international journal for chemical science

JF - Australian Journal of Chemistry:an international journal for chemical science

SN - 0004-9425

IS - 7

ER -

Synthesis and Structure of the Binuclear 1:1 Silver(I) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex

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