TY - JOUR
T1 - Synthesis and characterisation of a bis(silyloxy)tin(IV) porphyrin
AU - Langford, S.J.
AU - Latter, Melissa
AU - Beckmann, J.
PY - 2005
Y1 - 2005
N2 - Bis(hydroxy)tin(IV) tetraphenylporphyrin (Sn(IV)TPP(OH)2, 2) condenses with two equivalents of tris(tert-butoxy)silanol (HOSi((OBu)-Bu-t)(3), 3) to form complex 2.3(2)in toluene. The product, which is air and moisture stable, has been characterised by H-1, Si-29 and Sn-119 NMR spectroscopy and mass spectrometry. Application of this reaction in producing novel photochromic glasses is also discussed. (c) 2005 Elsevier B.V. All rights reserved.
AB - Bis(hydroxy)tin(IV) tetraphenylporphyrin (Sn(IV)TPP(OH)2, 2) condenses with two equivalents of tris(tert-butoxy)silanol (HOSi((OBu)-Bu-t)(3), 3) to form complex 2.3(2)in toluene. The product, which is air and moisture stable, has been characterised by H-1, Si-29 and Sn-119 NMR spectroscopy and mass spectrometry. Application of this reaction in producing novel photochromic glasses is also discussed. (c) 2005 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.inoche.2005.07.005
DO - 10.1016/j.inoche.2005.07.005
M3 - Article
SN - 1387-7003
VL - 8
SP - 920
EP - 923
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 10
ER -