Synthesis and characterisation of a bis(silyloxy)tin(IV) porphyrin

S.J. Langford, Melissa Latter, J. Beckmann

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

Bis(hydroxy)tin(IV) tetraphenylporphyrin (Sn(IV)TPP(OH)2, 2) condenses with two equivalents of tris(tert-butoxy)silanol (HOSi((OBu)-Bu-t)(3), 3) to form complex 2.3(2)in toluene. The product, which is air and moisture stable, has been characterised by H-1, Si-29 and Sn-119 NMR spectroscopy and mass spectrometry. Application of this reaction in producing novel photochromic glasses is also discussed. (c) 2005 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)920-923
JournalInorganic Chemistry Communications
Volume8
Issue number10
DOIs
Publication statusPublished - 2005

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