Syntheses, structural characterisation and electronic structures of some simple acyclic amino carbene complexes

Samantha Eaves; D.S. Yufit; Brian Skelton; J.A.K. Howard; Paul Low

doi:10.1039/c5dt01806d

Syntheses, structural characterisation and electronic structures of some simple acyclic amino carbene complexes

Samantha Eaves, D.S. Yufit, Brian Skelton, J.A.K. Howard, Paul Low

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

© The Royal Society of Chemistry 2015. Reactions of the vinylidene complexes [M(CCH2)(PP)Cp′]PF6 with NH3 readily afford the acyclic amino carbene complexes [M{C(Me)NH2}(PP)Cp′]PF6 [M(PP)Cp′ = Fe(dppe)Cp, Ru(dppe)Cp, Ru(PPh3)2Cp, Ru(dppe)Cp∗]. Crystallographic, spectroscopic and computational data support a description of these complexes in terms of a M-{C(Me)N⁺H2} mesomeric form, and simple σ-coordination of the singlet acyclic amino carbene.

Original language	English
Pages (from-to)	14341-14348
Journal	Dalton Transactions
Volume	44
Issue number	32
Early online date	30 Jun 2015
DOIs	https://doi.org/10.1039/c5dt01806d
Publication status	Published - 28 Aug 2015

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abstract = "{\textcopyright} The Royal Society of Chemistry 2015. Reactions of the vinylidene complexes [M(CCH2)(PP)Cp′]PF6 with NH3 readily afford the acyclic amino carbene complexes [M{C(Me)NH2}(PP)Cp′]PF6 [M(PP)Cp′ = Fe(dppe)Cp, Ru(dppe)Cp, Ru(PPh3)2Cp, Ru(dppe)Cp∗]. Crystallographic, spectroscopic and computational data support a description of these complexes in terms of a M-{C(Me)N+H2} mesomeric form, and simple σ-coordination of the singlet acyclic amino carbene.",

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AU - Eaves, Samantha

AU - Yufit, D.S.

AU - Skelton, Brian

AU - Howard, J.A.K.

AU - Low, Paul

PY - 2015/8/28

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N2 - © The Royal Society of Chemistry 2015. Reactions of the vinylidene complexes [M(CCH2)(PP)Cp′]PF6 with NH3 readily afford the acyclic amino carbene complexes [M{C(Me)NH2}(PP)Cp′]PF6 [M(PP)Cp′ = Fe(dppe)Cp, Ru(dppe)Cp, Ru(PPh3)2Cp, Ru(dppe)Cp∗]. Crystallographic, spectroscopic and computational data support a description of these complexes in terms of a M-{C(Me)N+H2} mesomeric form, and simple σ-coordination of the singlet acyclic amino carbene.

AB - © The Royal Society of Chemistry 2015. Reactions of the vinylidene complexes [M(CCH2)(PP)Cp′]PF6 with NH3 readily afford the acyclic amino carbene complexes [M{C(Me)NH2}(PP)Cp′]PF6 [M(PP)Cp′ = Fe(dppe)Cp, Ru(dppe)Cp, Ru(PPh3)2Cp, Ru(dppe)Cp∗]. Crystallographic, spectroscopic and computational data support a description of these complexes in terms of a M-{C(Me)N+H2} mesomeric form, and simple σ-coordination of the singlet acyclic amino carbene.

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DO - 10.1039/c5dt01806d

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SP - 14341

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JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Syntheses, structural characterisation and electronic structures of some simple acyclic amino carbene complexes

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