TY - JOUR
T1 - Syntheses and molecular structures of some phosphine-gold(I) derivatives of 1,3-diynes
AU - Bruce, M.I.
AU - Jevric, M.
AU - Skelton, Brian
AU - Smith, M.E.
AU - White, Allan
AU - Zaitseva, N.N.
PY - 2006
Y1 - 2006
N2 - The syntheses of several diynylgold(I) phosphine complexes, including Au(C CC CH){P(tol)(3)) (1), Au(C CC CSiMe3)(PR3) (R = Ph 2-Ph, tol 2-tol), Au(C CC CFc)(PPh3) (3), {(tol)(3)P}Au(C C)(n)Au{P(tol)(3)} [n = 2 (4), 3 (6), 4 (7)], ((Ph3P)Au)C CC C{Au[P(tol)(3)P(tol)(3)]} (5), [ppn][Au{C CC CAu[P(tol)(3)]}(2)] (8), [Au-2(mu-1)( t-dppm)(2)][Au(C CC CSiMC3)(2)] (9), Hg{C CC CAu(PR3)}(2) (R=Ph 10-Ph, tol 10-tol) and {(triphos)Cu) C CC C{Au[P(tol)(3)]} (11) are described. Of these, the X-ray molecular structures of 1, 2-tol, 3, 4 and 9 have been determined. (c) 2005 Elsevier B.V. All rights reserved.
AB - The syntheses of several diynylgold(I) phosphine complexes, including Au(C CC CH){P(tol)(3)) (1), Au(C CC CSiMe3)(PR3) (R = Ph 2-Ph, tol 2-tol), Au(C CC CFc)(PPh3) (3), {(tol)(3)P}Au(C C)(n)Au{P(tol)(3)} [n = 2 (4), 3 (6), 4 (7)], ((Ph3P)Au)C CC C{Au[P(tol)(3)P(tol)(3)]} (5), [ppn][Au{C CC CAu[P(tol)(3)]}(2)] (8), [Au-2(mu-1)( t-dppm)(2)][Au(C CC CSiMC3)(2)] (9), Hg{C CC CAu(PR3)}(2) (R=Ph 10-Ph, tol 10-tol) and {(triphos)Cu) C CC C{Au[P(tol)(3)]} (11) are described. Of these, the X-ray molecular structures of 1, 2-tol, 3, 4 and 9 have been determined. (c) 2005 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.jorganchem.2005.08.050
DO - 10.1016/j.jorganchem.2005.08.050
M3 - Article
VL - 691
SP - 361
EP - 370
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 3
ER -