Syntheses and Crystal Structures of Some CCo3 Clusters Containing PPh3 or dppm Ligands

M.I. Bruce; K.A. Kramarczuk; G.J. Perkins; Brian Skelton; Allan White; N.N. Zaitseva

doi:10.1023/B:JOCL.0000027397.89365.42

Syntheses and Crystal Structures of Some CCo3 Clusters Containing PPh3 or dppm Ligands

M.I. Bruce, K.A. Kramarczuk, G.J. Perkins, Brian Skelton, Allan White, N.N. Zaitseva

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Abstract

Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.

Original language	English
Pages (from-to)	119-137
Journal	Journal of Cluster Science
Volume	15
Issue number	2
DOIs	https://doi.org/10.1023/B:JOCL.0000027397.89365.42
Publication status	Published - 2004

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abstract = "Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.",

author = "M.I. Bruce and K.A. Kramarczuk and G.J. Perkins and Brian Skelton and Allan White and N.N. Zaitseva",

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AU - Bruce, M.I.

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AU - Perkins, G.J.

AU - Skelton, Brian

AU - White, Allan

AU - Zaitseva, N.N.

PY - 2004

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N2 - Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.

AB - Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.

U2 - 10.1023/B:JOCL.0000027397.89365.42

DO - 10.1023/B:JOCL.0000027397.89365.42

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VL - 15

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EP - 137

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 2

ER -

Syntheses and Crystal Structures of Some CCo3 Clusters Containing PPh3 or dppm Ligands

Abstract

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