Structural Systematics for Lanthanide(III) Systems: Interactions of the Achiral Hexamminecobalt(III) Cation with Tris(dipicolinato)lanthanate(III) Anions

Jack Mac B. Harrowfield; Irene Ling; Brian Warwick Skelton; Alexandre N Sobolev; Allan Henry White

doi:10.1071/CH16584

Structural Systematics for Lanthanide(III) Systems: Interactions of the Achiral Hexamminecobalt(III) Cation with Tris(dipicolinato)lanthanate(III) Anions

Jack Mac B. Harrowfield, Irene Ling, Brian Warwick Skelton, Alexandre N Sobolev, Allan Henry White

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Extended structural studies, largely determinations at ,150 K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3]
(Ln¼La–Lu, and Y; dipic¼dipicolinate¼pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature of
the interactions between the formally achiral cation and the chiral anions. They also provide a reference point for
consideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.

Original language	English
Pages (from-to)	485-493
Number of pages	9
Journal	Australian Journal of Chemistry
Volume	70
Issue number	5
DOIs	https://doi.org/10.1071/CH16584
Publication status	Published - 2017

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title = "Structural Systematics for Lanthanide(III) Systems: Interactions of the Achiral Hexamminecobalt(III) Cation with Tris(dipicolinato)lanthanate(III) Anions",

abstract = "Extended structural studies, largely determinations at ,150 K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3](Ln¼La–Lu, and Y; dipic¼dipicolinate¼pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature ofthe interactions between the formally achiral cation and the chiral anions. They also provide a reference point forconsideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.",

author = "Harrowfield, {Jack Mac B.} and Irene Ling and Skelton, {Brian Warwick} and Sobolev, {Alexandre N} and White, {Allan Henry}",

year = "2017",

doi = "10.1071/CH16584",

language = "English",

volume = "70",

pages = "485--493",

journal = "Australian Journal of Chemistry",

publisher = "CSIRO Publishing",

number = "5",

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T1 - Structural Systematics for Lanthanide(III) Systems: Interactions of the Achiral Hexamminecobalt(III) Cation with Tris(dipicolinato)lanthanate(III) Anions

AU - Harrowfield, Jack Mac B.

AU - Ling, Irene

AU - Skelton, Brian Warwick

AU - Sobolev, Alexandre N

AU - White, Allan Henry

PY - 2017

Y1 - 2017

N2 - Extended structural studies, largely determinations at ,150 K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3](Ln¼La–Lu, and Y; dipic¼dipicolinate¼pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature ofthe interactions between the formally achiral cation and the chiral anions. They also provide a reference point forconsideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.

AB - Extended structural studies, largely determinations at ,150 K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3](Ln¼La–Lu, and Y; dipic¼dipicolinate¼pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature ofthe interactions between the formally achiral cation and the chiral anions. They also provide a reference point forconsideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.

U2 - 10.1071/CH16584

DO - 10.1071/CH16584

M3 - Article

VL - 70

SP - 485

EP - 493

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 5

ER -

Structural Systematics for Lanthanide(III) Systems: Interactions of the Achiral Hexamminecobalt(III) Cation with Tris(dipicolinato)lanthanate(III) Anions

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