Structural Systematics for Lanthanide(III) Systems: Interactions of the Achiral Hexamminecobalt(III) Cation with Tris(dipicolinato)lanthanate(III) Anions

Jack Mac B. Harrowfield, Irene Ling, Brian Warwick Skelton, Alexandre N Sobolev, Allan Henry White

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Extended structural studies, largely determinations at ,150 K, of the family of hydrates of [Co(NH3)6][Ln(dipic)3]
(Ln¼La–Lu, and Y; dipic¼dipicolinate¼pyridine-2,6-dicarboxylate) have provided detailed evidence of the nature of
the interactions between the formally achiral cation and the chiral anions. They also provide a reference point for
consideration of related systems incorporating chiral cations with and without the capacity to act as H-bond donors.
Original languageEnglish
Pages (from-to)485-493
Number of pages9
JournalAustralian Journal Chemistry
Volume70
Issue number5
Publication statusPublished - 2017

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