TY - JOUR
T1 - Structural forms in complexes of 2,9-dimenthyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species
AU - Mutrofin, S.
AU - Chan, Eric
AU - Healy, P.C.
AU - Marinelli, A.
AU - Ngoune, J.
AU - Pettinari, C.
AU - Pettinari, R.
AU - Somers, N.
AU - Skelton, Brian
AU - White, Allan
PY - 2008
Y1 - 2008
N2 - Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO3: dmp: MeCN (1:1:1), 'dmp' =2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(NN) Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)(2)](+) cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride. (C) 2007 Elsevier B. V. All rights reserved.
AB - Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO3: dmp: MeCN (1:1:1), 'dmp' =2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(NN) Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)(2)](+) cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride. (C) 2007 Elsevier B. V. All rights reserved.
U2 - 10.1016/j.ica.2007.11.009
DO - 10.1016/j.ica.2007.11.009
M3 - Article
SN - 0020-1693
VL - 361
SP - 2365
EP - 2374
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -