Structural Consequences of S → Se Substitution in some Symmetrical [M(S2CNR2)3] Complexes

W. Dietzsch, N.V. Duffy, A.M. Lee, Brian Skelton, Allan White

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5 Citations (Scopus)

Abstract

The consequences of replacement of the symmetrically chelate ligands in [M(E2CNR2)(3)] (E=S, Se) complexes of potential 32 symmetry by analogous mixed S,Se unsymmetrical chelates are explored for both small (M=Co) and large (M=In) metal atoms, and R=primary (Et) and secondary (Pr-1) alkyl substituents by way of low-temperature single crystal X-ray studies of [(Co(SSeCNEt2)(3)] ([CO(Se2CNEt2)(3)] also determined as datum), and [In(SSeCNR2)(3)], R=Et, Pr-i. The structure of [((Pr2N)-Pr-i center dot CS center dot Se)(2)] is also recorded.
Original languageEnglish
Pages (from-to)2419-2423
JournalZeitschrift fuer Anorganische und Allgemeine Chemie
Volume632
Issue number15
DOIs
Publication statusPublished - 2006

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