Sterically induced transmutations in cobalt amine chemistry

R.J. Geue; C.J. Qin; S.F. Ralph; A.M. Sargeson; Brian Skelton; Allan White; A.C. Willis

doi:10.1039/a907237c

Sterically induced transmutations in cobalt amine chemistry

R.J. Geue
, C.J. Qin
, S.F. Ralph
, A.M. Sargeson
, Brian Skelton
, Allan White
, A.C. Willis

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to (CoN6)-N-III/II redox potentials close to +0.8 V (vs. SHE) and Co-II hexaamine complexes that are air and substitution stable.

Original language	English
Pages (from-to)	2351-2352
Journal	Chemical Communications
Volume	N/A
Issue number	N/A
DOIs	https://doi.org/10.1039/a907237c
Publication status	Published - 1999

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title = "Sterically induced transmutations in cobalt amine chemistry",

abstract = "Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to (CoN6)-N-III/II redox potentials close to +0.8 V (vs. SHE) and Co-II hexaamine complexes that are air and substitution stable.",

author = "R.J. Geue and C.J. Qin and S.F. Ralph and A.M. Sargeson and Brian Skelton and Allan White and A.C. Willis",

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language = "English",

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T1 - Sterically induced transmutations in cobalt amine chemistry

AU - Geue, R.J.

AU - Qin, C.J.

AU - Ralph, S.F.

AU - Sargeson, A.M.

AU - Skelton, Brian

AU - White, Allan

AU - Willis, A.C.

PY - 1999

Y1 - 1999

N2 - Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to (CoN6)-N-III/II redox potentials close to +0.8 V (vs. SHE) and Co-II hexaamine complexes that are air and substitution stable.

AB - Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to (CoN6)-N-III/II redox potentials close to +0.8 V (vs. SHE) and Co-II hexaamine complexes that are air and substitution stable.

U2 - 10.1039/a907237c

DO - 10.1039/a907237c

M3 - Article

SN - 1359-7345

VL - N/A

SP - 2351

EP - 2352

JO - Chemical Communications

JF - Chemical Communications

IS - N/A

ER -

Sterically induced transmutations in cobalt amine chemistry

Abstract

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