Stereochemistry of cage amine complexes-probing the ligand conformational flexibility with hydrogen bonds

I. Ling, Alexandre Sobolev, R. Hashim, J.M. Harrowfield

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4 Citations (Scopus)

Abstract

© 2014 The Royal Society of Chemistry. Structure determinations for some Co(iii) complexes of simple derivatives of the cage hexamine 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane ("sarcophagine") show that there is no evidence that the H-bonding involving the NH centres of the complex cations is influenced by electronic effects due to the substituents. "H-bond chelation" of chloride anions or water molecules results in retention of the symmetrical lel3 conformation. This journal is
Original languageEnglish
Pages (from-to)11058-11063
JournalCrystEngComm
Volume16
Issue number48
Early online date5 Nov 2014
DOIs
Publication statusPublished - 2014

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