Stereochemistry of cage amine complexes-probing the ligand conformational flexibility with hydrogen bonds

I. Ling; Alexandre Sobolev; R. Hashim; J.M. Harrowfield

doi:10.1039/c4ce01980f

Stereochemistry of cage amine complexes-probing the ligand conformational flexibility with hydrogen bonds

I. Ling, Alexandre Sobolev, R. Hashim, J.M. Harrowfield

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

© 2014 The Royal Society of Chemistry. Structure determinations for some Co(iii) complexes of simple derivatives of the cage hexamine 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane ("sarcophagine") show that there is no evidence that the H-bonding involving the NH centres of the complex cations is influenced by electronic effects due to the substituents. "H-bond chelation" of chloride anions or water molecules results in retention of the symmetrical lel3 conformation. This journal is

Original language	English
Pages (from-to)	11058-11063
Journal	CrystEngComm
Volume	16
Issue number	48
Early online date	5 Nov 2014
DOIs	https://doi.org/10.1039/c4ce01980f
Publication status	Published - 2014

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AU - Sobolev, Alexandre

AU - Hashim, R.

AU - Harrowfield, J.M.

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AB - © 2014 The Royal Society of Chemistry. Structure determinations for some Co(iii) complexes of simple derivatives of the cage hexamine 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane ("sarcophagine") show that there is no evidence that the H-bonding involving the NH centres of the complex cations is influenced by electronic effects due to the substituents. "H-bond chelation" of chloride anions or water molecules results in retention of the symmetrical lel3 conformation. This journal is

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DO - 10.1039/c4ce01980f

M3 - Article

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Stereochemistry of cage amine complexes-probing the ligand conformational flexibility with hydrogen bonds

Abstract

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