Spectroscopic and computational studies of the ligand redox non-innocence in mono- and binuclear ruthenium vinyl complexes

W.Y. Man; J.-L. Xia; N.J. Brown; J.D. Farmer; D.S. Yufit; J.A.K. Howard; S.H. Liu; Paul Low

doi:10.1021/om1010534

Spectroscopic and computational studies of the ligand redox non-innocence in mono- and binuclear ruthenium vinyl complexes

W.Y. Man, J.-L. Xia, N.J. Brown, J.D. Farmer, D.S. Yufit, J.A.K. Howard, S.H. Liu, Paul Low

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

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Abstract

A combination of IR spectroelectrochemistry and DFT calculations has been used to demonstrate that the vinyl ligands in the complexes [Ru(CH═CHC6H4Me-4)Cl(CO)(PMe3)3] and [{RuCl(CO)(PMe3)3}2(μ-CH═CHC6H4CH═CH)] are redox noninnocent, and one-electron oxidation results in radical cations that are best described in terms of metal-stabilized organic radicals.

Original language	English
Pages (from-to)	1852-1858
Journal	Organometallics
Volume	30
Issue number	7
Early online date	10 Mar 2011
DOIs	https://doi.org/10.1021/om1010534
Publication status	Published - 11 Apr 2011

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10.1021/om1010534

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title = "Spectroscopic and computational studies of the ligand redox non-innocence in mono- and binuclear ruthenium vinyl complexes",

abstract = "A combination of IR spectroelectrochemistry and DFT calculations has been used to demonstrate that the vinyl ligands in the complexes [Ru(CH═CHC6H4Me-4)Cl(CO)(PMe3)3] and [{RuCl(CO)(PMe3)3}2(μ-CH═CHC6H4CH═CH)] are redox noninnocent, and one-electron oxidation results in radical cations that are best described in terms of metal-stabilized organic radicals.",

author = "W.Y. Man and J.-L. Xia and N.J. Brown and J.D. Farmer and D.S. Yufit and J.A.K. Howard and S.H. Liu and Paul Low",

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T1 - Spectroscopic and computational studies of the ligand redox non-innocence in mono- and binuclear ruthenium vinyl complexes

AU - Man, W.Y.

AU - Xia, J.-L.

AU - Brown, N.J.

AU - Farmer, J.D.

AU - Yufit, D.S.

AU - Howard, J.A.K.

AU - Liu, S.H.

AU - Low, Paul

PY - 2011/4/11

Y1 - 2011/4/11

N2 - A combination of IR spectroelectrochemistry and DFT calculations has been used to demonstrate that the vinyl ligands in the complexes [Ru(CH═CHC6H4Me-4)Cl(CO)(PMe3)3] and [{RuCl(CO)(PMe3)3}2(μ-CH═CHC6H4CH═CH)] are redox noninnocent, and one-electron oxidation results in radical cations that are best described in terms of metal-stabilized organic radicals.

AB - A combination of IR spectroelectrochemistry and DFT calculations has been used to demonstrate that the vinyl ligands in the complexes [Ru(CH═CHC6H4Me-4)Cl(CO)(PMe3)3] and [{RuCl(CO)(PMe3)3}2(μ-CH═CHC6H4CH═CH)] are redox noninnocent, and one-electron oxidation results in radical cations that are best described in terms of metal-stabilized organic radicals.

U2 - 10.1021/om1010534

DO - 10.1021/om1010534

M3 - Article

SN - 0276-7333

VL - 30

SP - 1852

EP - 1858

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Spectroscopic and computational studies of the ligand redox non-innocence in mono- and binuclear ruthenium vinyl complexes

Abstract

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