Soot particle morphology and nanostructure with oxygenated fuels: A comparative study into cold-start and hot-start operation

Puneet Verma, Mohammad Jafari, Ali Zare, Edmund Pickering, Yi Guo, Chiemeriwo Godday Osuagwu, Svetlana Stevanovic, Richard Brown, Zoran Ristovski

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

This study investigates the morphology and nanostructure of soot particles during cold-start and hot-start engine operation of a diesel engine using oxygenated fuels. The soot samples were analysed using transmission electron microscopy. The oxygen content in the fuel was varied between 0 and 12%. The results showed that the primary particles during cold-start have significantly smaller size when compared to hot-start engine operation. The addition of oxygenated fuels also resulted in smaller sized primary particles. Smaller radius of gyration and higher fractal dimension of soot aggregates during cold-start would mean smaller aggregate size with a more compact structure. Shorter fringes with a higher inter-fringe spacing for cold-start would mean lower graphitisation of soot particles that could be related to higher oxidation reactivity of soot particles.
Original languageEnglish
Article number116592
JournalEnvironmental Pollution
Volume275
DOIs
Publication statusPublished - 15 Apr 2021
Externally publishedYes

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