Some reactions of the ruthenium allenylidene complex [Ru(C=C=CPh2)(PPh3)(2)Cp][PF6] with nucleophiles

MI Bruce, PJ Low, ERT Tiekink

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Abstract

Reactions between [Ru(C=C=CPh2)(PPh3)(2)Cp][PF6] and nucleophilic reagents LiMe, NaOMe, KCN and KC5H5 have given the neutral substituted alkynyl-ruthenium complexes Ru{C=CCPh2(Nu)} (PPh3)(2)Cp. The molecular structures of complexes with Nu = OMe. CN and C5H5 have been determined. (C) 1999 Elsevier Science S.A. All rights reserved.

Original languageEnglish
Pages (from-to)3-10
Number of pages8
JournalJournal of Organometallic Chemistry
Volume572
Issue number1
DOIs
Publication statusPublished - 5 Jan 1999

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