TY - JOUR
T1 - Some Alkynyl-Ruthenium Complexes Containing Di-Imine and Tertiary Phosphine Ligands
AU - Bruce, M.I.
AU - Hall, B.C.
AU - Skelton, Brian
AU - White, Allan
PY - 2008
Y1 - 2008
N2 - Reactions between [RuCl2(PPh3)(2)(Bu(2)(t)bpy)], (1), and terminal alkynes in the presence of T1[PF6], followed by chromatography on alumina, have given the mono-alkynyl complexes [RuCl(C CR)(PPh3)(2)(Bu(2)(t)bpy)] (R = Ph 2, C6H4NO2-4 3, CO2Me 4, Fc 5, CPh2(OH) 6), of which the single-crystal XRD molecular structures of 3, 4 and 5 are reported.
AB - Reactions between [RuCl2(PPh3)(2)(Bu(2)(t)bpy)], (1), and terminal alkynes in the presence of T1[PF6], followed by chromatography on alumina, have given the mono-alkynyl complexes [RuCl(C CR)(PPh3)(2)(Bu(2)(t)bpy)] (R = Ph 2, C6H4NO2-4 3, CO2Me 4, Fc 5, CPh2(OH) 6), of which the single-crystal XRD molecular structures of 3, 4 and 5 are reported.
U2 - 10.1002/zaac.200800020
DO - 10.1002/zaac.200800020
M3 - Article
SN - 0044-2313
VL - 634
SP - 1097
EP - 1101
JO - Zeitschrift fuer Anorganische und Allgemeine Chemie
JF - Zeitschrift fuer Anorganische und Allgemeine Chemie
IS - 6-7
ER -