Some Alkynyl-Ruthenium Complexes Containing Di-Imine and Tertiary Phosphine Ligands

M.I. Bruce, B.C. Hall, Brian Skelton, Allan White

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Reactions between [RuCl2(PPh3)(2)(Bu(2)(t)bpy)], (1), and terminal alkynes in the presence of T1[PF6], followed by chromatography on alumina, have given the mono-alkynyl complexes [RuCl(C CR)(PPh3)(2)(Bu(2)(t)bpy)] (R = Ph 2, C6H4NO2-4 3, CO2Me 4, Fc 5, CPh2(OH) 6), of which the single-crystal XRD molecular structures of 3, 4 and 5 are reported.
Original languageEnglish
Pages (from-to)1097-1101
JournalZeitschrift fuer Anorganische und Allgemeine Chemie
Volume634
Issue number6-7
DOIs
Publication statusPublished - 2008

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