Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxan

N.L. Armanasco; Murray Baker; David Brown; J.M. Harrowfield; Brian Skelton; Allan White

doi:10.1016/j.ica.2004.07.012

Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxan

N.L. Armanasco, Murray Baker, David Brown, J.M. Harrowfield, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Low-temperature, single crystal X-ray structural characterisations of trans-[NiCl2(HOMe)4], trans-O-[Ni(MeOH)2(μ-Cl)(2/2)2](∞mid∞) · 0.5dioxan and trans-trans-[Ni(H2O)2Cl2(O-dioxan-O)(2/2)](∞mid∞) · dioxan are recorded, offering intriguing insights into O-donor/Ni(II) relativities. All nickel atoms in all structures are located on crystallographic inversion centres, the last two compounds being one-dimensional polymers.

Original language	English
Pages (from-to)	4562-4567
Journal	Inorganica Chimica Acta
Volume	357
Issue number	15
DOIs	https://doi.org/10.1016/j.ica.2004.07.012
Publication status	Published - 2004

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title = "Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxan",

abstract = "Low-temperature, single crystal X-ray structural characterisations of trans-[NiCl2(HOMe)4], trans-O-[Ni(MeOH)2(μ-Cl)(2/2)2](∞mid∞) · 0.5dioxan and trans-trans-[Ni(H2O)2Cl2(O-dioxan-O)(2/2)](∞mid∞) · dioxan are recorded, offering intriguing insights into O-donor/Ni(II) relativities. All nickel atoms in all structures are located on crystallographic inversion centres, the last two compounds being one-dimensional polymers.",

author = "N.L. Armanasco and Murray Baker and David Brown and J.M. Harrowfield and Brian Skelton and Allan White",

year = "2004",

doi = "10.1016/j.ica.2004.07.012",

language = "English",

volume = "357",

pages = "4562--4567",

journal = "Inorganica Chimica Acta",

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publisher = "Elsevier Science & Technology",

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T1 - Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxan

AU - Armanasco, N.L.

AU - Baker, Murray

AU - Brown, David

AU - Harrowfield, J.M.

AU - Skelton, Brian

AU - White, Allan

PY - 2004

Y1 - 2004

N2 - Low-temperature, single crystal X-ray structural characterisations of trans-[NiCl2(HOMe)4], trans-O-[Ni(MeOH)2(μ-Cl)(2/2)2](∞mid∞) · 0.5dioxan and trans-trans-[Ni(H2O)2Cl2(O-dioxan-O)(2/2)](∞mid∞) · dioxan are recorded, offering intriguing insights into O-donor/Ni(II) relativities. All nickel atoms in all structures are located on crystallographic inversion centres, the last two compounds being one-dimensional polymers.

AB - Low-temperature, single crystal X-ray structural characterisations of trans-[NiCl2(HOMe)4], trans-O-[Ni(MeOH)2(μ-Cl)(2/2)2](∞mid∞) · 0.5dioxan and trans-trans-[Ni(H2O)2Cl2(O-dioxan-O)(2/2)](∞mid∞) · dioxan are recorded, offering intriguing insights into O-donor/Ni(II) relativities. All nickel atoms in all structures are located on crystallographic inversion centres, the last two compounds being one-dimensional polymers.

U2 - 10.1016/j.ica.2004.07.012

DO - 10.1016/j.ica.2004.07.012

M3 - Article

SN - 0020-1693

VL - 357

SP - 4562

EP - 4567

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 15

ER -

Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxan

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