Single-Crystal X-Ray Diffraction Study of Pressure and Temperature-Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework

Gemma F. Turner, Fallyn Campbell, Stephen A. Moggach, Simon Parsons, Andrés E. Goeta, M. Carmen Muñoz, José A. Real

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

High-pressure single-crystal X-ray diffraction has been used to trap both the low-spin (LS) and high-spin (HS) states of the iron(II) Hofmann spin crossover framework, [FeII(pdm)(H2O)[Ag(CN)2]2⋅H2O, under identical experimental conditions, allowing the structural changes arising from the spin-transition to be deconvoluted from previously reported thermal effects.

Original languageEnglish
Pages (from-to)3106-3111
JournalAngewandte Chemie - International Edition
Volume59
Issue number8
DOIs
Publication statusPublished - 1 Jan 2019

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