Silver(i), gold(i) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: A comparison with pyridyl analogues

J. Vaughan; D.J. Carter; A.L. Rohl; M.I. Ogden; Brian Skelton; P.V. Simpson; D.H. Brown

doi:10.1039/c5dt04213e

Silver(i), gold(i) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: A comparison with pyridyl analogues

J. Vaughan, D.J. Carter, A.L. Rohl, M.I. Ogden, Brian Skelton, P.V. Simpson, D.H. Brown

Centre for Microscopy, Characterisation & Analysis

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

© 2016 The Royal Society of Chemistry. Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms.

Original language	English
Pages (from-to)	1484-1495
Number of pages	12
Journal	Dalton Transactions
Volume	45
Issue number	4
DOIs	https://doi.org/10.1039/c5dt04213e
Publication status	Published - 2016

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title = "Silver(i), gold(i) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: A comparison with pyridyl analogues",

abstract = "{\textcopyright} 2016 The Royal Society of Chemistry. Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms.",

author = "J. Vaughan and D.J. Carter and A.L. Rohl and M.I. Ogden and Brian Skelton and P.V. Simpson and D.H. Brown",

year = "2016",

doi = "10.1039/c5dt04213e",

language = "English",

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pages = "1484--1495",

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T1 - Silver(i), gold(i) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: A comparison with pyridyl analogues

AU - Vaughan, J.

AU - Carter, D.J.

AU - Rohl, A.L.

AU - Ogden, M.I.

AU - Skelton, Brian

AU - Simpson, P.V.

AU - Brown, D.H.

PY - 2016

Y1 - 2016

N2 - © 2016 The Royal Society of Chemistry. Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms.

AB - © 2016 The Royal Society of Chemistry. Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms.

U2 - 10.1039/c5dt04213e

DO - 10.1039/c5dt04213e

M3 - Article

C2 - 26672744

SN - 1477-9226

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EP - 1495

JO - Dalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry

JF - Dalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry

IS - 4

ER -

Silver(i), gold(i) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: A comparison with pyridyl analogues

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