TY - JOUR
T1 - Silver(I) cis-diphenylphosphinoethylene complexes: Spectroscopic and structural characterization
AU - Pettinari, C.
AU - Marinelli, A.
AU - Pizzabiocca, A.
AU - Effendy, [No Value]
AU - Skelton, Brian
AU - White, Allan
PY - 2009
Y1 - 2009
N2 - Adducts of the diphosphine cis-Ph2P(CHdouble bond; length as m-dashCH)PPh2 (L) with AgX (X = NO3, BF4, ClO4 or CF3SO3) have been synthesized and characterized both in solution (1H, 31P NMR) and in the solid state (IR, single crystal X-ray structure analysis). The topologies of the structures in the solid state were found to depend on the nature of the counter-ion X. The adduct AgNO3:L (2:1)2 is tetranuclear, derivative of the chair form, the bidentate ligands bridging peripheral silver centers, the nitrates being coordinated through two oxygen atoms, the first O,O′-bridging the second bridging bidentate.
AB - Adducts of the diphosphine cis-Ph2P(CHdouble bond; length as m-dashCH)PPh2 (L) with AgX (X = NO3, BF4, ClO4 or CF3SO3) have been synthesized and characterized both in solution (1H, 31P NMR) and in the solid state (IR, single crystal X-ray structure analysis). The topologies of the structures in the solid state were found to depend on the nature of the counter-ion X. The adduct AgNO3:L (2:1)2 is tetranuclear, derivative of the chair form, the bidentate ligands bridging peripheral silver centers, the nitrates being coordinated through two oxygen atoms, the first O,O′-bridging the second bridging bidentate.
U2 - 10.1016/j.inoche.2008.11.003
DO - 10.1016/j.inoche.2008.11.003
M3 - Article
SN - 1387-7003
VL - 12
SP - 55
EP - 57
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 1
ER -