Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene

A.J. Petrella; N.K. Roberts; D.C. Craig; Colin Raston; R.N. Lamb

Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene

A.J. Petrella
, N.K. Roberts
, D.C. Craig
, Colin Raston
, R.N. Lamb

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of p-tBu-calix[6]arene with potassium metal in methanol followed by [TiCp2Cl2] affords novel mononuclear and binuclear monocyclopentadienyl titanium(IV) complexes, both having the same inverted double cone conformation with a Cp in one of the cavities, in both complexes.

Original language	English
Pages (from-to)	1014-1015
Journal	Chemical Communications
Volume	8
Issue number	8
Publication status	Published - 2003

Cite this

@article{6280e8d4a0154a02a2ea59d5bd452b20,

title = "Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene",

abstract = "Reaction of p-tBu-calix[6]arene with potassium metal in methanol followed by [TiCp2Cl2] affords novel mononuclear and binuclear monocyclopentadienyl titanium(IV) complexes, both having the same inverted double cone conformation with a Cp in one of the cavities, in both complexes.",

author = "A.J. Petrella and N.K. Roberts and D.C. Craig and Colin Raston and R.N. Lamb",

year = "2003",

language = "English",

volume = "8",

pages = "1014--1015",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "8",

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TY - JOUR

T1 - Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene

AU - Petrella, A.J.

AU - Roberts, N.K.

AU - Craig, D.C.

AU - Raston, Colin

AU - Lamb, R.N.

PY - 2003

Y1 - 2003

N2 - Reaction of p-tBu-calix[6]arene with potassium metal in methanol followed by [TiCp2Cl2] affords novel mononuclear and binuclear monocyclopentadienyl titanium(IV) complexes, both having the same inverted double cone conformation with a Cp in one of the cavities, in both complexes.

AB - Reaction of p-tBu-calix[6]arene with potassium metal in methanol followed by [TiCp2Cl2] affords novel mononuclear and binuclear monocyclopentadienyl titanium(IV) complexes, both having the same inverted double cone conformation with a Cp in one of the cavities, in both complexes.

M3 - Article

SN - 1359-7345

VL - 8

SP - 1014

EP - 1015

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene

Abstract

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