Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene

A.J. Petrella, N.K. Roberts, D.C. Craig, Colin Raston, R.N. Lamb

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Reaction of p-tBu-calix[6]arene with potassium metal in methanol followed by [TiCp2Cl2] affords novel mononuclear and binuclear monocyclopentadienyl titanium(IV) complexes, both having the same inverted double cone conformation with a Cp in one of the cavities, in both complexes.
Original languageEnglish
Pages (from-to)1014-1015
JournalChemical Communications
Volume8
Issue number8
Publication statusPublished - 2003

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