Reactions of transition metal σ-acetylides. VII. Synthesis and properties of complexes containing halovinylidene ligands. X-ray structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3]

Michael I. Bruce, George A. Koutsantonis, Michael J. Liddell, Brian K. Nicholson

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

Addition of halogen (Cl2, Br2 or I2) to ruthenium or osmium acetylide complexes has afforded cationic halovinylidene derivatives; in one case, halogenation of the phenyl group of a phenylacetylide ligand also occurred. The structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3] has been determined; crystals are monoclinic, space group P21/c, with a 18.693(5), b 15.460(5), c 15.679(5) Å, β 101.49(2)° and Z 4; 5180 data with I > 2σ(I) were refined to R 0.045, Rw 0.051. Significant distances are RuC 1.839(7), CC 1.31(1) Å; angle RuCC is 171.0(7)°.

Original languageEnglish
Pages (from-to)217-227
Number of pages11
JournalJournal of Organometallic Chemistry
Volume320
Issue number2
DOIs
Publication statusPublished - 10 Feb 1987
Externally publishedYes

Fingerprint

Halogenation
Osmium
Halogens
Ruthenium
Transition metals
Metals
transition metals
Ligands
X-Rays
halogenation
Derivatives
X rays
Crystals
ligands
osmium
synthesis
halogens
ruthenium
x rays
crystals

Cite this

@article{a16cc9da069b40afba399bf412aa12a9,
title = "Reactions of transition metal σ-acetylides. VII. Synthesis and properties of complexes containing halovinylidene ligands. X-ray structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3]",
abstract = "Addition of halogen (Cl2, Br2 or I2) to ruthenium or osmium acetylide complexes has afforded cationic halovinylidene derivatives; in one case, halogenation of the phenyl group of a phenylacetylide ligand also occurred. The structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3] has been determined; crystals are monoclinic, space group P21/c, with a 18.693(5), b 15.460(5), c 15.679(5) {\AA}, β 101.49(2)° and Z 4; 5180 data with I > 2σ(I) were refined to R 0.045, Rw 0.051. Significant distances are RuC 1.839(7), CC 1.31(1) {\AA}; angle RuCC is 171.0(7)°.",
author = "Bruce, {Michael I.} and Koutsantonis, {George A.} and Liddell, {Michael J.} and Nicholson, {Brian K.}",
year = "1987",
month = "2",
day = "10",
doi = "10.1016/S0022-328X(00)98978-2",
language = "English",
volume = "320",
pages = "217--227",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier Science & Technology",
number = "2",

}

Reactions of transition metal σ-acetylides. VII. Synthesis and properties of complexes containing halovinylidene ligands. X-ray structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3]. / Bruce, Michael I.; Koutsantonis, George A.; Liddell, Michael J.; Nicholson, Brian K.

In: Journal of Organometallic Chemistry, Vol. 320, No. 2, 10.02.1987, p. 217-227.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Reactions of transition metal σ-acetylides. VII. Synthesis and properties of complexes containing halovinylidene ligands. X-ray structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3]

AU - Bruce, Michael I.

AU - Koutsantonis, George A.

AU - Liddell, Michael J.

AU - Nicholson, Brian K.

PY - 1987/2/10

Y1 - 1987/2/10

N2 - Addition of halogen (Cl2, Br2 or I2) to ruthenium or osmium acetylide complexes has afforded cationic halovinylidene derivatives; in one case, halogenation of the phenyl group of a phenylacetylide ligand also occurred. The structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3] has been determined; crystals are monoclinic, space group P21/c, with a 18.693(5), b 15.460(5), c 15.679(5) Å, β 101.49(2)° and Z 4; 5180 data with I > 2σ(I) were refined to R 0.045, Rw 0.051. Significant distances are RuC 1.839(7), CC 1.31(1) Å; angle RuCC is 171.0(7)°.

AB - Addition of halogen (Cl2, Br2 or I2) to ruthenium or osmium acetylide complexes has afforded cationic halovinylidene derivatives; in one case, halogenation of the phenyl group of a phenylacetylide ligand also occurred. The structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3] has been determined; crystals are monoclinic, space group P21/c, with a 18.693(5), b 15.460(5), c 15.679(5) Å, β 101.49(2)° and Z 4; 5180 data with I > 2σ(I) were refined to R 0.045, Rw 0.051. Significant distances are RuC 1.839(7), CC 1.31(1) Å; angle RuCC is 171.0(7)°.

UR - http://www.scopus.com/inward/record.url?scp=0000210824&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)98978-2

DO - 10.1016/S0022-328X(00)98978-2

M3 - Article

VL - 320

SP - 217

EP - 227

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 2

ER -