TY - JOUR
T1 - Reactions of transition metal σ-acetylides. VII. Synthesis and properties of complexes containing halovinylidene ligands. X-ray structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3]
AU - Bruce, Michael I.
AU - Koutsantonis, George A.
AU - Liddell, Michael J.
AU - Nicholson, Brian K.
PY - 1987/2/10
Y1 - 1987/2/10
N2 - Addition of halogen (Cl2, Br2 or I2) to ruthenium or osmium acetylide complexes has afforded cationic halovinylidene derivatives; in one case, halogenation of the phenyl group of a phenylacetylide ligand also occurred. The structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3] has been determined; crystals are monoclinic, space group P21/c, with a 18.693(5), b 15.460(5), c 15.679(5) Å, β 101.49(2)° and Z 4; 5180 data with I > 2σ(I) were refined to R 0.045, Rw 0.051. Significant distances are RuC 1.839(7), CC 1.31(1) Å; angle RuCC is 171.0(7)°.
AB - Addition of halogen (Cl2, Br2 or I2) to ruthenium or osmium acetylide complexes has afforded cationic halovinylidene derivatives; in one case, halogenation of the phenyl group of a phenylacetylide ligand also occurred. The structure of [Ru(CCIPh)(PPh3)2(η-C5H5)][I3] has been determined; crystals are monoclinic, space group P21/c, with a 18.693(5), b 15.460(5), c 15.679(5) Å, β 101.49(2)° and Z 4; 5180 data with I > 2σ(I) were refined to R 0.045, Rw 0.051. Significant distances are RuC 1.839(7), CC 1.31(1) Å; angle RuCC is 171.0(7)°.
UR - http://www.scopus.com/inward/record.url?scp=0000210824&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)98978-2
DO - 10.1016/S0022-328X(00)98978-2
M3 - Article
AN - SCOPUS:0000210824
SN - 0022-328X
VL - 320
SP - 217
EP - 227
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -