Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand

C.S. Griffith, George Koutsantonis, Brian Skelton, Allan White

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Carbon ligand transfer: Compound 1 is formed with reactive metal–ligand fragments generated from Group 4 metallocene compounds. Dropwise addition of ethanolic HCl to a solution of complex 1 in toluene affords complex 2 in a carbon–carbon bond-forming transformation that is thought to be unprecedented.
Original languageEnglish
Pages (from-to)3038-3043
JournalAngewandte Chemie (International Edition)
Volume44
Issue number20
DOIs
Publication statusPublished - 2005

Fingerprint Dive into the research topics of 'Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand'. Together they form a unique fingerprint.

Cite this