Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand

C.S. Griffith; George Koutsantonis; Brian Skelton; Allan White

doi:10.1002/anie.200500224

Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand

C.S. Griffith, George Koutsantonis, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Carbon ligand transfer: Compound 1 is formed with reactive metal–ligand fragments generated from Group 4 metallocene compounds. Dropwise addition of ethanolic HCl to a solution of complex 1 in toluene affords complex 2 in a carbon–carbon bond-forming transformation that is thought to be unprecedented.

Original language	English
Pages (from-to)	3038-3043
Journal	Angewandte Chemie (International Edition)
Volume	44
Issue number	20
DOIs	https://doi.org/10.1002/anie.200500224
Publication status	Published - 2005

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10.1002/anie.200500224

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title = "Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand",

abstract = "Carbon ligand transfer: Compound 1 is formed with reactive metal–ligand fragments generated from Group 4 metallocene compounds. Dropwise addition of ethanolic HCl to a solution of complex 1 in toluene affords complex 2 in a carbon–carbon bond-forming transformation that is thought to be unprecedented.",

author = "C.S. Griffith and George Koutsantonis and Brian Skelton and Allan White",

year = "2005",

doi = "10.1002/anie.200500224",

language = "English",

volume = "44",

pages = "3038--3043",

journal = "Angewandte Chemie (International Edition)",

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publisher = "Wiley-VCH Verlag GmbH & Co. KGaA",

number = "20",

}

Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand. / Griffith, C.S.; Koutsantonis, George ; Skelton, Brian et al.
In: Angewandte Chemie (International Edition), Vol. 44, No. 20, 2005, p. 3038-3043.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand

AU - Griffith, C.S.

AU - Koutsantonis, George

AU - Skelton, Brian

AU - White, Allan

PY - 2005

Y1 - 2005

N2 - Carbon ligand transfer: Compound 1 is formed with reactive metal–ligand fragments generated from Group 4 metallocene compounds. Dropwise addition of ethanolic HCl to a solution of complex 1 in toluene affords complex 2 in a carbon–carbon bond-forming transformation that is thought to be unprecedented.

AB - Carbon ligand transfer: Compound 1 is formed with reactive metal–ligand fragments generated from Group 4 metallocene compounds. Dropwise addition of ethanolic HCl to a solution of complex 1 in toluene affords complex 2 in a carbon–carbon bond-forming transformation that is thought to be unprecedented.

U2 - 10.1002/anie.200500224

DO - 10.1002/anie.200500224

M3 - Article

SN - 1433-7851

VL - 44

SP - 3038

EP - 3043

JO - Angewandte Chemie (International Edition)

JF - Angewandte Chemie (International Edition)

IS - 20

ER -

Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand

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