Preparation and molecular structure of a pyrazolyl–ruthenium complex, Ru{C3H2NN(SO2tol)}(dppe)Cp*

M.I. Bruce; B.G. Ellis; Brian Skelton; Allan White

doi:10.1016/j.jorganchem.2003.11.022

Preparation and molecular structure of a pyrazolyl–ruthenium complex, Ru{C3H2NN(SO2tol)}(dppe)Cp*

M.I. Bruce
, B.G. Ellis
, Brian Skelton
, Allan White

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative Image (1), which was characterised by a single-crystal X-ray structure determination. Complex 1 is probably formed by attack of the NTs group on the π-complexed desilylated alkyne, with concomitant loss of a proton.The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative (1), which was characterised by a single-crystal X-ray structure determination.

Original language	English
Pages (from-to)	698-701
Journal	Journal of Organometallic Chemistry
Volume	689
Issue number	3
DOIs	https://doi.org/10.1016/j.jorganchem.2003.11.022
Publication status	Published - 2004

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title = "Preparation and molecular structure of a pyrazolyl–ruthenium complex, Ru\{C3H2NN(SO2tol)\}(dppe)Cp*",

abstract = "The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative Image (1), which was characterised by a single-crystal X-ray structure determination. Complex 1 is probably formed by attack of the NTs group on the π-complexed desilylated alkyne, with concomitant loss of a proton.The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative (1), which was characterised by a single-crystal X-ray structure determination.",

author = "M.I. Bruce and B.G. Ellis and Brian Skelton and Allan White",

year = "2004",

doi = "10.1016/j.jorganchem.2003.11.022",

language = "English",

volume = "689",

pages = "698--701",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "3",

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TY - JOUR

T1 - Preparation and molecular structure of a pyrazolyl–ruthenium complex, Ru{C3H2NN(SO2tol)}(dppe)Cp*

AU - Bruce, M.I.

AU - Ellis, B.G.

AU - Skelton, Brian

AU - White, Allan

PY - 2004

Y1 - 2004

N2 - The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative Image (1), which was characterised by a single-crystal X-ray structure determination. Complex 1 is probably formed by attack of the NTs group on the π-complexed desilylated alkyne, with concomitant loss of a proton.The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative (1), which was characterised by a single-crystal X-ray structure determination.

AB - The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative Image (1), which was characterised by a single-crystal X-ray structure determination. Complex 1 is probably formed by attack of the NTs group on the π-complexed desilylated alkyne, with concomitant loss of a proton.The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative (1), which was characterised by a single-crystal X-ray structure determination.

U2 - 10.1016/j.jorganchem.2003.11.022

DO - 10.1016/j.jorganchem.2003.11.022

M3 - Article

SN - 0022-328X

VL - 689

SP - 698

EP - 701

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Preparation and molecular structure of a pyrazolyl–ruthenium complex, Ru{C3H2NN(SO2tol)}(dppe)Cp*

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