Preparation and molecular structure of a pyrazolyl–ruthenium complex, Ru{C3H2NN(SO2tol)}(dppe)Cp*

M.I. Bruce, B.G. Ellis, Brian Skelton, Allan White

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative Image (1), which was characterised by a single-crystal X-ray structure determination. Complex 1 is probably formed by attack of the NTs group on the π-complexed desilylated alkyne, with concomitant loss of a proton.The reaction between RuCl(dppe)Cp* and Me3SiCCC(SiMe3)NNHTs has given the pyrazole derivative (1), which was characterised by a single-crystal X-ray structure determination.
Original languageEnglish
Pages (from-to)698-701
JournalJournal of Organometallic Chemistry
Volume689
Issue number3
DOIs
Publication statusPublished - 2004

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