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Abstract
A convenient, inexpensive synthesis of the previously reported, well-defined complex Ni(tmeda)(o-tol)Cl is described. This protocol enables rapid and safe access to Ni(tmeda)(o-tol)Cl, obviating the use of the hazardous reagent AlMe3 or air-sensitive Ni(COD)2. Ni(tmeda)(o-tol)Cl is prepared at room temperature from commercially available and easily synthesized precursor Ni(acac)2 and can be isolated at gram scale in air via simple filtration. We expect this simple method to be attractive to chemical industry and academia given the types of solvents, reaction temperature, and reagents used.
Original language | English |
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Pages (from-to) | 4485-4491 |
Number of pages | 7 |
Journal | Organic Process Research and Development |
Volume | 28 |
Issue number | 12 |
Early online date | 15 Nov 2024 |
DOIs | |
Publication status | Published - 2024 |
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Dive into the research topics of 'Practical, Large-Scale Preparation of Ni(tmeda)(o-tol)Cl'. Together they form a unique fingerprint.Projects
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Counting the Electrons: Nickel Catalysed Electrochemical C-H Activation
Stewart, S. (Investigator 01), Koutsantonis, G. (Investigator 02) & Dorta, R. (Investigator 03)
ARC Australian Research Council
1/01/23 → 28/02/26
Project: Research