Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Ross J. Marshall; Tom Richards; Claire L. Hobday; Colin F. Murphie; Claire Wilson; Stephen A. Moggach; Thomas D. Bennett; Ross S. Forgan

doi:10.1039/c5dt03178h

Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Ross J. Marshall
, Tom Richards
, Claire L. Hobday
, Colin F. Murphie
, Claire Wilson
, Stephen A. Moggach
, Thomas D. Bennett
, Ross S. Forgan

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

Original language	English
Pages (from-to)	4132-4135
Number of pages	4
Journal	Dalton Transactions
Volume	45
Issue number	10
DOIs	https://doi.org/10.1039/c5dt03178h
Publication status	Published - 2016
Externally published	Yes

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10.1039/c5dt03178hLicence: CC BY

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title = "Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance",

abstract = "A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.",

keywords = "METAL-ORGANIC FRAMEWORKS, ZEOLITIC IMIDAZOLATE FRAMEWORKS, SINGLE-CRYSTAL, FUNCTIONALIZATION, STABILITY, LIGAND",

author = "Marshall, \{Ross J.\} and Tom Richards and Hobday, \{Claire L.\} and Murphie, \{Colin F.\} and Claire Wilson and Moggach, \{Stephen A.\} and Bennett, \{Thomas D.\} and Forgan, \{Ross S.\}",

year = "2016",

doi = "10.1039/c5dt03178h",

language = "English",

volume = "45",

pages = "4132--4135",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "The Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - Postsynthetic bromination of UiO-66 analogues

T2 - altering linker flexibility and mechanical compliance

AU - Marshall, Ross J.

AU - Richards, Tom

AU - Hobday, Claire L.

AU - Murphie, Colin F.

AU - Wilson, Claire

AU - Moggach, Stephen A.

AU - Bennett, Thomas D.

AU - Forgan, Ross S.

PY - 2016

Y1 - 2016

N2 - A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

AB - A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

KW - METAL-ORGANIC FRAMEWORKS

KW - ZEOLITIC IMIDAZOLATE FRAMEWORKS

KW - SINGLE-CRYSTAL

KW - FUNCTIONALIZATION

KW - STABILITY

KW - LIGAND

U2 - 10.1039/c5dt03178h

DO - 10.1039/c5dt03178h

M3 - Article

SN - 1477-9226

VL - 45

SP - 4132

EP - 4135

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

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