Polymerisation of a Cu(II) dimer into 1D chains using high pressure

Stephen A. Moggach; Kyle W. Galloway; Alistair R. Lennie; Pascal Parois; Niall Rowantree; Euan K. Brechin; John E. Warren; Mark Murrie; Simon Parsons

doi:10.1039/b912707k

Polymerisation of a Cu(II) dimer into 1D chains using high pressure

Stephen A. Moggach, Kyle W. Galloway, Alistair R. Lennie, Pascal Parois, Niall Rowantree, Euan K. Brechin, John E. Warren, Mark Murrie, Simon Parsons

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Long intermolecular interactions are converted into covalent bonds when the complex [Cu(2)(OH)(citrate)(Guanidine)2](-) is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.

Original language	English
Pages (from-to)	2601-2604
Number of pages	4
Journal	CrystEngComm
Volume	11
Issue number	12
DOIs	https://doi.org/10.1039/b912707k
Publication status	Published - 2009
Externally published	Yes

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10.1039/b912707k

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title = "Polymerisation of a Cu(II) dimer into 1D chains using high pressure",

abstract = "Long intermolecular interactions are converted into covalent bonds when the complex [Cu(2)(OH)(citrate)(Guanidine)2](-) is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.",

keywords = "CRYSTAL-STRUCTURE, CHEMISTRY, COMPLEX",

author = "Moggach, {Stephen A.} and Galloway, {Kyle W.} and Lennie, {Alistair R.} and Pascal Parois and Niall Rowantree and Brechin, {Euan K.} and Warren, {John E.} and Mark Murrie and Simon Parsons",

year = "2009",

doi = "10.1039/b912707k",

language = "English",

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T1 - Polymerisation of a Cu(II) dimer into 1D chains using high pressure

AU - Moggach, Stephen A.

AU - Galloway, Kyle W.

AU - Lennie, Alistair R.

AU - Parois, Pascal

AU - Rowantree, Niall

AU - Brechin, Euan K.

AU - Warren, John E.

AU - Murrie, Mark

AU - Parsons, Simon

PY - 2009

Y1 - 2009

N2 - Long intermolecular interactions are converted into covalent bonds when the complex [Cu(2)(OH)(citrate)(Guanidine)2](-) is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.

AB - Long intermolecular interactions are converted into covalent bonds when the complex [Cu(2)(OH)(citrate)(Guanidine)2](-) is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.

KW - CRYSTAL-STRUCTURE

KW - CHEMISTRY

KW - COMPLEX

U2 - 10.1039/b912707k

DO - 10.1039/b912707k

M3 - Article

SN - 1466-8033

VL - 11

SP - 2601

EP - 2604

JO - CrystEngComm

JF - CrystEngComm

IS - 12

ER -

Polymerisation of a Cu(II) dimer into 1D chains using high pressure

Abstract

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