TY - JOUR
T1 - Polydentate tertiary amine aluminium hydride adducts
T2 - Monomeric versus polymeric species
AU - Atwood, Jerry L.
AU - Bennett, Frederick R.
AU - Jones, Cameron
AU - Koutsantonis, George A.
AU - Raston, Colin L.
AU - Robinson, Kerry D.
PY - 1992/12/1
Y1 - 1992/12/1
N2 - Treatment of H3AlNMe3 with 1,3,5-trimethylhexahydro- 1,3,5-triazine (tmtz) yields trigonal bipyramidal, monomeric [H 3Al(tmtz)2], 1, or polymeric [H3Al(tmtz)] ∞, 2, which undergo N-CH2 cleavage at ca. 123°C; nitrogen-atoms in 1 and 2 are in apical positions, as also established for polymeric [H3Al(N,N,N′,N′-tetramethylpropylenediamine)] ∞, in accordance with ab initio molecular orbital calculations on the model system H3Al(NH3)2.
AB - Treatment of H3AlNMe3 with 1,3,5-trimethylhexahydro- 1,3,5-triazine (tmtz) yields trigonal bipyramidal, monomeric [H 3Al(tmtz)2], 1, or polymeric [H3Al(tmtz)] ∞, 2, which undergo N-CH2 cleavage at ca. 123°C; nitrogen-atoms in 1 and 2 are in apical positions, as also established for polymeric [H3Al(N,N,N′,N′-tetramethylpropylenediamine)] ∞, in accordance with ab initio molecular orbital calculations on the model system H3Al(NH3)2.
UR - http://www.scopus.com/inward/record.url?scp=37049076030&partnerID=8YFLogxK
U2 - 10.1039/C39920000541
DO - 10.1039/C39920000541
M3 - Article
AN - SCOPUS:37049076030
SN - 0022-4936
SP - 541
EP - 543
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 7
ER -