Poly-carbon chemistry: reactions of the multi-site coordinated diyndiyl ligand in {Fe-2(CO)(6)(mu-PPh2)}(2)(mu-eta(1),eta(2):mu-eta(1),eta(2)-C C-C C) with the nucleophiles P(OMe)(3) and NHEt2

PJ Low, AJ Carty, KA Udachin, GD Enright

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Abstract

The diyndiyl complex {Fe-2(CO)(6)(mu -PPh2)}(2)(mu -C=C-C=C) reacts with P(OMe)(3) or NHEt2 to give products derived from addition to C-alpha and facile P-C, N-C and/or C-C bond formation.

Original languageEnglish
Pages (from-to)411-412
Number of pages2
JournalChemical Communications
Issue number5
DOIs
Publication statusPublished - 2001

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