Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Irene Ling, Harshita Kumari, Marzieh Mirzamani, Alexandre N. Sobolev, Christopher J. Garvey, Jerry L. Atwood, Colin L. Raston

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

Original languageEnglish
Pages (from-to)10824-10827
Number of pages4
JournalChemical Communications
Volume54
Issue number77
DOIs
Publication statusPublished - 4 Oct 2018

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