Perfluorocarbon liquid under pressure: a medium for gas delivery

Scott C. McKellar; Jorge Sotelo; John P. S. Mowat; Paul A. Wright; Stephen A. Moggach

doi:10.1039/c5ce01989c

Perfluorocarbon liquid under pressure: a medium for gas delivery

Scott C. McKellar, Jorge Sotelo, John P. S. Mowat, Paul A. Wright, Stephen A. Moggach

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A novel method for CO2 delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO2 has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO2.

Original language	English
Pages (from-to)	1273-1276
Number of pages	4
Journal	CrystEngComm
Volume	18
Issue number	8
DOIs	https://doi.org/10.1039/c5ce01989c
Publication status	Published - 2016
Externally published	Yes

Access to Document

10.1039/c5ce01989c

Cite this

@article{410d193f7e8845b2b65a507320df5727,

title = "Perfluorocarbon liquid under pressure: a medium for gas delivery",

abstract = "A novel method for CO2 delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO2 has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO2.",

keywords = "METAL-ORGANIC FRAMEWORKS, PORE SCANDIUM TEREPHTHALATE, CARBON-DIOXIDE, BLOOD SUBSTITUTES, PHASE-TRANSITION, OXYGEN CARRIERS, CO2 CAPTURE, SC-2(O2CC6H4CO2)(3), CHEMISTRY, CAPACITY",

author = "McKellar, {Scott C.} and Jorge Sotelo and Mowat, {John P. S.} and Wright, {Paul A.} and Moggach, {Stephen A.}",

year = "2016",

doi = "10.1039/c5ce01989c",

language = "English",

volume = "18",

pages = "1273--1276",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "ROYAL SOC CHEMISTRY",

number = "8",

}

TY - JOUR

T1 - Perfluorocarbon liquid under pressure

T2 - a medium for gas delivery

AU - McKellar, Scott C.

AU - Sotelo, Jorge

AU - Mowat, John P. S.

AU - Wright, Paul A.

AU - Moggach, Stephen A.

PY - 2016

Y1 - 2016

N2 - A novel method for CO2 delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO2 has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO2.

AB - A novel method for CO2 delivery to a porous material is reported, wherein a perfluorocarbon containing dissolved CO2 has been used as a pressure-transmitting liquid in a high-pressure single-crystal X-ray diffraction experiment. Pressure causes the gas to be squeezed out of the liquid into the host crystal, monitored via a single-crystal to single-crystal phase transition on uptake of CO2.

KW - METAL-ORGANIC FRAMEWORKS

KW - PORE SCANDIUM TEREPHTHALATE

KW - CARBON-DIOXIDE

KW - BLOOD SUBSTITUTES

KW - PHASE-TRANSITION

KW - OXYGEN CARRIERS

KW - CO2 CAPTURE

KW - SC-2(O2CC6H4CO2)(3)

KW - CHEMISTRY

KW - CAPACITY

U2 - 10.1039/c5ce01989c

DO - 10.1039/c5ce01989c

M3 - Article

SN - 1466-8033

VL - 18

SP - 1273

EP - 1276

JO - CrystEngComm

JF - CrystEngComm

IS - 8

ER -

Perfluorocarbon liquid under pressure: a medium for gas delivery

Abstract

Access to Document

Fingerprint

Cite this